Demeton-o sulfoxide

Base Information

• Chemical Name: Demeton-o sulfoxide
• CAS No.: 5286-73-7
• Molecular Formula: C8H19O4PS2
• Molecular Weight: 274.3378
• Hs Code.: 2930909090
• UNII: O06U450254
• DSSTox Substance ID: DTXSID40863515
• Nikkaji Number: J50.463G
• Wikidata: Q27285153
• Mol file: 5286-73-7.mol

Synonyms:Demeton-o sulfoxide;Systox sulfoxide;5286-73-7;Demeton-O-sulfoxide;BRN 1712524;Diethyl 2-eththionylethyl thionophosphate;O,O-Diethyl O-(2-eththionylethyl)phosphorothioate;UNII-O06U450254;diethoxy-(2-ethylsulfinylethoxy)-sulfanylidene-lambda5-phosphane;O06U450254;PHOSPHOROTHIOIC ACID, O,O-DIETHYL O-(2-(ETHYLSULFINYL)ETHYL) ESTER;Phosphorothioic acid, O,O-diethyl O-[2-(ethylsulfinyl)ethyl] ester;DTXSID40863515;LS-108620;O,O-Diethyl O-2-ethylsulfinylethyl phosphorothioate;Q27285153;O,O-Diethyl o-[2-(ethylsulfinyl)ethyl] thiophosphate #;O-[2-(Ethanesulfinyl)ethyl] O,O-diethyl phosphorothioate;diethoxy-(2-ethylsulfinylethoxy)-sulfanylidene-?^{5}-phosphane

Chemical Property of Demeton-o sulfoxide

Chemical Property:

• Vapor Pressure: 1.72E-05mmHg at 25°C
• Boiling Point: 375.1°Cat760mmHg
• Flash Point: 180.6°C
• PSA: 105.87000
• Density: 1.24g/cm³
• LogP: 3.58540
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 274.04623843
• Heavy Atom Count: 15
• Complexity: 225

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOP(=S)(OCC)OCCS(=O)CC

Technology Process of Demeton-o sulfoxide

There total 2 articles about Demeton-o sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

demeton-O (298-03-3) → thiophosphoric acid O-(2-ethanesulfinyl-ethyl) ester O',O''-diethyl ester (5286-73-7)

Guidance literature:

With perfluoro cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); at -30 ℃; for 60h; Product distribution; other temp.;

DOI:10.1016/0040-4020(95)00413-3

Reference yield:

→ thiophosphoric acid O-(2-ethanesulfinyl-ethyl) ester O',O''-diethyl ester (5286-73-7)

Guidance literature:

DOI:10.1021/jf60146a014

Reference yield: 90.0%

thiophosphoric acid O-(2-ethanesulfinyl-ethyl) ester O',O''-diethyl ester (5286-73-7) → phosphoric acid-(2-ethanesulfinyl-ethyl ester)-diethyl ester (23052-55-3)

Guidance literature:

With perfluoro-cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); at -30 ℃; for 6h;

DOI:10.1021/jo970572a

upstream raw materials:

demeton-O

Downstream raw materials:

phosphoric acid-(2-ethanesulfinyl-ethyl ester)-diethyl ester

Refernces