(3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane

Base Information

• Chemical Name: (3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane
• CAS No.: 13837-95-1
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.237
• Hs Code.: 2902199090
• DSSTox Substance ID: DTXSID50160643
• Nikkaji Number: J109.980I
• Wikidata: Q83029000
• Mol file: 13837-95-1.mol

Synonyms:13837-95-1;(3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane;1-METHYLENE-3-(1-METHYLETHENYL)-CYCLOHEXANE (R);m-Mentha-1(7),8-diene, (R)-(-)-;Cyclohexane, 1-methylene-3-(1-methylethenyl)-, (R)-;(3R)-1-METHYLIDENE-3-PROP-1-EN-2-YL-CYCLOHEXANE;DTXSID50160643;IRKOFIFCPOQHKY-SNVBAGLBSA-N;1-Isopropenyl-3-methylenecyclohexane #;[R,(?)]-m-Mentha-1(7),8-diene

Chemical Property of (3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane

Chemical Property:

• Vapor Pressure: 1.49mmHg at 25°C
• Boiling Point: 176.1°Cat760mmHg
• Flash Point: 45.7°C
• PSA: 0.00000
• Density: 0.82g/cm³
• LogP: 3.30890
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 136.125200510
• Heavy Atom Count: 10
• Complexity: 153

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=C)C1CCCC(=C)C1
• Isomeric SMILES: CC(=C)[C@@H]1CCCC(=C)C1

Technology Process of (3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane

There total 2 articles about (3R)-1-methylidene-3-prop-1-en-2-ylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

'd-Silvestrene-dihydrochloride' (4497-93-2,23516-31-6,23516-32-7,24278-78-2,24278-79-3) → 1(7),8-m-Menthadien, β-Silvestren (13837-95-1)

Guidance literature:

With sodium acetate; acetic acid;

Reference yield:

(+)-Δ3-carene (498-15-7,19079-29-9) → 1(7),8-m-Menthadien, β-Silvestren (13837-95-1)

Guidance literature:

Multistep reaction; (i) aq. HCl, (ii) NaOAc, AcOH;

DOI:10.1016/S0040-4039(01)89298-4

Reference yield:

1(7),8-m-Menthadien, β-Silvestren (13837-95-1) → (1S,3R)-(+)-cis-m-Menthan (13837-66-6)

Guidance literature:

With hydrogen; nickel;

upstream raw materials:

(+)-Δ³-carene

'd-Silvestrene-dihydrochloride'

Downstream raw materials:

(1S,3R)-(+)-cis-m-Menthan

(1R,3R)-(+)-trans-m-Menthan