Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside

Base Information

Chemical Name:Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside
CAS No.:6386-19-2
Molecular Formula:C14H17 N3 O4
Molecular Weight:292.3099
Hs Code.:
DSSTox Substance ID:DTXSID20411199,DTXSID80978435
NSC Number:287056,287048

Synonyms:62774-39-4;6386-19-2;AC1NQJIO;DTXSID20411199;DTXSID80978435;Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside;NSC287048;NSC287056;NSC-287048;NSC-287056

Suppliers and Price of Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：86.67000
Density:g/cm³
LogP:1.99366
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:291.12190603
Heavy Atom Count:21
Complexity:396

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1CC(C2C(O1)COC(O2)C3=CC=CC=C3)N=[N+]=[N-]

Technology Process of Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside

There total 1 articles about Methyl 3-azido-4,6-O-benzylidene-2,3-dideoxyhexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6386-19-2
methyl 3-azido-4,6-O-benzylidene-2,3-dideoxy-α-D-arabino-hexopyranoside

Guidance literature:: aus 2 u.NaN3;
DOI:10.1016/S0008-6215(00)80201-3

Reference yield: 76.0%

: 6386-19-2
methyl 3-azido-4,6-O-benzylidene-2,3-dideoxy-α-D-arabino-hexopyranoside

: 18933-62-5
methyl 3-azido-4-O-benzoyl-6-bromo-2,3,6-trideoxy-α-D-arabino-hexopyranoside

Guidance literature:: With N-Bromosuccinimide; barium carbonate; In tetrachloromethane;
DOI:10.1248/cpb.30.1929

Reference yield:

: 6386-19-2
methyl 3-azido-4,6-O-benzylidene-2,3-dideoxy-α-D-arabino-hexopyranoside

: 83532-10-9
methyl 3-(N-benzyloxycarbonylamino)-2,3,6-trideoxy-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / N-bromosuccinimide, barium carbonate / CCl₄

2: 1.) H₂, triethylamine / 1.) Raney nickel / 1.) methanol, 2.) methanol, 3.) methanol

With N-Bromosuccinimide; hydrogen; triethylamine; barium carbonate; nickel; In tetrachloromethane;
DOI:10.1248/cpb.30.1929