Technology Process of Gold, (benzenethiolato)(triphenylphosphine)-
There total 2 articles about Gold, (benzenethiolato)(triphenylphosphine)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
to soln. of Au-complex in THF was added Sn-complex, refluxed for 20 h under N2; solvent was distilled off at reduced pressure, treated with hexane, extd. with benzene, recrystd. from benzene-hexane; elem. anal.;
DOI:10.1016/S0020-1693(00)00353-4
- Guidance literature:
-
With
triethyl amine;
In
tetrahydrofuran;
byproducts: HN(C2H5)3Cl; dropwise addn. of mixt. of thiol and N(C2H5)3 in THF to soln. of gold compound in THF at room temp., under dry purified N2; stirring for 1 h;; evapn. of solvent under reduced pressure; trituration with water; filtration after 30 min; 2 fold washing with water and min. amt. of CH3OH; drying in vac.; recrystn. from benzene/n-hexane; elem. anal.;;
- Guidance literature:
-
In
dichloromethane;
diffusion of ether into a soln. of the starting compds. in CH2Cl2;
DOI:10.1107/S0108270193006043
