1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione

Base Information

Chemical Name:1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione
CAS No.:81640-32-6
Molecular Formula:C₈H₈O₃
Molecular Weight:152.15
Hs Code.:
Mol file:81640-32-6.mol

Synonyms:1,5-dimethyl-bicyclo<3.1.0>hexan-2,3,4-trion;Bicyclo(3.1.0)hexane-2,3,4-trione,1,5-dimethyl;

Suppliers and Price of 1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of 1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione

Chemical Property:

Vapor Pressure:0.0764mmHg at 25°C
Boiling Point:227.7°Cat760mmHg
Flash Point:87.8°C
PSA：51.21000
Density:1.429g/cm³
LogP:0.12360

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione

There total 2 articles about 1,5-dimethylbicyclo[3.1.0]hexane-2,3,4-trione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: (1R,5S)-3-Diazo-1,5-dimethyl-bicyclo[3.1.0]hexane-2,4-dione

: 81640-32-6
1,5-dimethyl-bicyclo<3.1.0>hexan-2,3,4-trion

Guidance literature:: With tert-butylhypochlorite; In water; acetonitrile; at 0 ℃;
DOI:10.1016/S0040-4039(01)83012-4

Reference yield:

: 29978-55-0
(1R,5S)-1,5-Dimethyl-bicyclo[3.1.0]hexane-2,4-dione

: 81640-32-6
1,5-dimethyl-bicyclo<3.1.0>hexan-2,3,4-trion

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / DABCO, p-Nitrobenzolsulfonsaeureazid / formamide / Ambient temperature

2: 40 percent / t-Butylhypochlorit / acetonitrile; H₂O / 0 °C

With 1,4-diaza-bicyclo[2.2.2]octane; tert-butylhypochlorite; p-Nitrobenzolsulfonsaeureazid; In water; formamide; acetonitrile;
DOI:10.1016/S0040-4039(01)83012-4