CID 5487803

Base Information

• Chemical Name: CID 5487803
• CAS No.: 12596-54-2
• Molecular Formula: Mo₂
• Molecular Weight: 191.88
• Mol file: 12596-54-2.mol

Synonyms:

Chemical Property of CID 5487803

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 193.810078
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Mo].[Mo]

Technology Process of CID 5487803

There total 4 articles about CID 5487803 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4K(1+)*2Mo(2+)*4SO4(2-)=K4Mo2(SO4)4 → Mo2(4+) (12596-54-2)

Guidance literature:

With Ba(CF₃SO₃)2; CF₃SO₃H; In water; byproducts: BaSO4; under Ar; prepd. soln. 0.10 M in Ba(CF3SO3)2 and 1 M in CF3SO3H in water, to this soln. added stoich. amt. of K4Mo2(SO4)4, stirred for 1 h at 25 ° C; BaSO4 sepd. by filtration; Mo2(4+) not isolated from soln.;

Reference yield:

3K(1+)*Mo2(5+)*4SO4(2-)*3.5H2O=K3Mo2(SO4)4*3.5H2O (63311-41-1) → Mo2(4+) (12596-54-2)

Guidance literature:

In hydrogenchloride; (N2); for 5 min at room temp.; not isolated, detected spectrofotometrically;

DOI:10.1021/ic50216a059

Reference yield:

molybdenum hexacarbonyl (13939-06-5,199620-15-0) → molybdenum dimer (12596-54-2) + Mo3 + 2Mo*CO=Mo2(CO)

Guidance literature:

In neat (no solvent, gas phase); Irradiation (UV/VIS); UV multiphoton excitation of gaseous Mo(CO)6 using XeCl lasers yields gas phase formation of Mo2, Mo2(CO)1 and Mo3.; Mo2 is spectroscopically identified.; Kinetics;

upstream raw materials:

molybdenum hexacarbonyl

molybdenum

3K⁽¹⁺⁾*Mo₂⁽⁵⁺⁾*4SO₄^(2-)*3.5H₂O=K₃Mo₂(SO₄)4*3.5H₂O

Refernces

• 1、 Cotton, F. Albert,Falvello, Larry R.,Murillo, Carlos A.. "Preparation and structure of crystalline tetrakis(D-mandelato)dimolybdenum(II) bis(tetrahydrofuranate)". . p. 382 - 387. Retrieved 2008/10/08.