(1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid

Base Information

Chemical Name:(1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid
CAS No.:20134-29-6
Molecular Formula:C20H26O7
Molecular Weight:378.42
Hs Code.:
DSSTox Substance ID:DTXSID401339951
Nikkaji Number:J4.753H
Wikidata:Q105032670
Mol file:20134-29-6.mol

(1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid

Synonyms:20134-29-6;(1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid;Gibberellin A23;DTXSID401339951;4a|A-Formyl-2|A,7-dihydroxy-1|A-methyl-8-methylenegibbane-1|A,10|A-dicarboxylic acid;(1 alpha,2 beta,4a alpha,4b beta,10 beta)-4a-Formyl-2,7-dihydroxy-1-methyl-8-methylenegibbane-1,10-dicarboxylic acid;(1S, 2S, 3S, 4S, 5S, 8R, 9R, 12S)-8-formyl-5, 12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01, 9.03, 8]pentadecane-2, 4-dicarboxylic acid

Suppliers and Price of (1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of (1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:597.091°C at 760 mmHg
Flash Point:328.939°C
PSA：132.13000
Density:1.445g/cm³
LogP:1.22540
XLogP3:0.1
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:378.16785316
Heavy Atom Count:27
Complexity:761

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C(CCC2(C1C(C34C2CCC(C3)(C(=C)C4)O)C(=O)O)C=O)O)C(=O)O
Isomeric SMILES:C[C@]1([C@H](CC[C@@]2([C@@H]1[C@@H]([C@]34[C@H]2CC[C@](C3)(C(=C)C4)O)C(=O)O)C=O)O)C(=O)O
Uses Gibberellin A23 is a derivative of the plant hormone Gibberellin which regulates growth and various developmental processes.

Technology Process of (1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid

There total 3 articles about (1S,2S,3S,4S,5S,8R,9R,12S)-8-Formyl-5,12-dihydroxy-4-methyl-13-methylidenetetracyclo[10.2.1.01,9.03,8]pentadecane-2,4-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₄₂O₉

: 20134-29-6
gibberellin A₂₃

Guidance literature:: With Dowex resin (H⁺); In methanol; water; for 0.666667h; Heating;
DOI:10.1016/S0031-9422(02)00442-9

Reference yield:

: C₃₂H₄₆O₉

: 20134-29-6
gibberellin A₂₃

Guidance literature:: Multi-step reaction with 2 steps

1: 58 mg / aq. NaOH / methanol / 15 h / Heating

2: 25 mg / Dowex resin (H⁺) / methanol; H₂O / 0.67 h / Heating

With sodium hydroxide; Dowex resin (H⁺); In methanol; water;
DOI:10.1016/S0031-9422(02)00442-9