Technology Process of Germanamine, 1-fluoro-N,1,1-tris(2,4,6-trimethylphenyl)-
There total 1 articles about Germanamine, 1-fluoro-N,1,1-tris(2,4,6-trimethylphenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
pentane; benzene;
byproducts: LiF; under inert gas; addn. of soln. of C6H2(CH3)3NHLi (5.6 mmol) in THF to soln. of (C6H2(CH3)3)2GeF2 (5.6 mmol) in benzene/pentane; storing for 24 h at 20°C;; centrifugfing LiF, evapg. solvent from supernatant liquid; taking up residue in pentane; recrystn. from pentane at -30°C; elem. anal.;;
- Guidance literature:
-
In
benzene;
byproducts: LiF; under inert gas; addn. of tert-butyllithium (0.37 mmol) in pentane (1.6 M) to soln. of (C6H2(CH3)3)2Ge(F)N(H)C6H2(CH3)3 (0.37 mmol) in benzene at 0°C;; pptn. at ambient temp.; washing with pentane, taking up in benzene; heating for 17 h to 50°C in sealed tube; centrifuging LiF, evapg. solvent;;
- Guidance literature:
-
In
benzene;
byproducts: LiF; under inert gas; addn. of tert-butyllithium (0.89 mmol) in pentane (1.6 M) to soln. of (C6H2(CH3)3)2Ge(F)N(H)C6H2(CH3)3 (0.89 mmol) in C6H6 (cooled to 5°C); stirring for 15 min; heating for 48 h to 50°C in sealed tube;; centrifuging LiF, evapg. solvent; pptn. from pentane; elem. anal.;;
