1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans-

Base Information

Chemical Name:1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans-
CAS No.:143925-30-8
Molecular Formula:C₂₂H₃₀O₈S
Molecular Weight:454.541
Hs Code.:
Mol file:143925-30-8.mol

Synonyms:

Suppliers and Price of 1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans-

Chemical Property:

Purity/Quality:

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Technology Process of 1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans-

There total 6 articles about 1,1-Cyclopentanedicarboxylic acid, 3-(2-methoxy-2-oxoethyl)-4-[[(4-methylphenyl)sulfonyl]methyl]-, diethyl ester, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 143925-28-4,144015-99-6,144016-00-2,144016-01-3
Diethyl cis-3-(Bromo(methoxycarbonyl)methyl)-4-(tosylmethyl)cyclopentane-1,1-dicarboxylate

: 143925-29-5,143925-30-8
Diethyl cis-3-((Methoxycarbonyl)methyl)-4-(tosylmethyl)cyclopentane-1,1-dicarboxylate

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; Heating;
DOI:10.1021/jo00049a014

Reference yield:

: 1117-71-1,56699-18-4,6000-00-6
methyl-4-bromo-2-butenoate

: 143925-29-5,143925-30-8
Diethyl cis-3-((Methoxycarbonyl)methyl)-4-(tosylmethyl)cyclopentane-1,1-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 1) NaH / 1) DMF, 0 deg C, then rt, 0.5 h, 2) rt, 24 h

2: acetonitrile / 30 h / 18 °C / Irradiation

3: 59 percent / Bu₃SnH, AIBN / toluene / Heating

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium hydride; In toluene; acetonitrile;
DOI:10.1021/jo00049a014

Reference yield:

: 2049-80-1
(2-propenyl)propanedioic acid diethyl ester

: 143925-29-5,143925-30-8
Diethyl cis-3-((Methoxycarbonyl)methyl)-4-(tosylmethyl)cyclopentane-1,1-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 1) NaH / 1) DMF, 0 deg C, then rt, 0.5 h, 2) rt, 24 h

2: acetonitrile / 30 h / 18 °C / Irradiation

3: 59 percent / Bu₃SnH, AIBN / toluene / Heating

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium hydride; In toluene; acetonitrile;
DOI:10.1021/jo00049a014