(13β)-12-Deoxylycocernuine

Base Information

• Chemical Name: (13β)-12-Deoxylycocernuine
• CAS No.: 15216-34-9
• Molecular Formula: C₁₆H₂₆N₂O
• Molecular Weight: 262.395
• Mol file: 15216-34-9.mol

Synonyms:Lycocernuine,12-deoxy-, (13b)-;Allocernuine

Chemical Property of (13β)-12-Deoxylycocernuine

Chemical Property:

• Boiling Point: 402.0±24.0 °C(Predicted)
• PKA: 9.07±0.40(Predicted)
• PSA: 23.55000
• Density: 1.13±0.1 g/cm3(Predicted)
• LogP: 2.62610

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (13β)-12-Deoxylycocernuine

There total 3 articles about (13β)-12-Deoxylycocernuine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

dehydrocernuine (1028132-58-2) → cernuine (6880-84-8,15216-34-9,15216-36-1)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In ethanol; at 20 ℃; for 2h;

DOI:10.1021/ol800574v

Reference yield:

→ Allocernuin (15216-34-9)

Guidance literature:

Anhydrohycocernuin, H2, PtO2, in E.;

DOI:10.1139/v67-077

Reference yield:

→ Cernuin (6880-84-8,15216-34-9,15216-36-1)

Guidance literature:

Biosynthese aus Pelletierin;

DOI:10.1039/C29700000409

upstream raw materials:

dehydrocernuine

Refernces

• 1、 Nishikawa, Yasuhiro,Kitajima, Mariko,Kogure, Noriyuki,Takayama, Hiromitsu. "A divergent approach for the total syntheses of cernuane-type and quinolizidine-type Lycopodium alkaloids". experimental part. p. 1608 - 1617. Retrieved 2009/05/09.