10-(chloromethyl)benzo[pqr]tetraphene

Base Information

Chemical Name:10-(chloromethyl)benzo[pqr]tetraphene
CAS No.:86803-19-2
Molecular Formula:C21H13Cl
Molecular Weight:300.7809
Hs Code.:

Synonyms:

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 10-(chloromethyl)benzo[pqr]tetraphene

Chemical Property:

Vapor Pressure:1.81E-10mmHg at 25°C
Boiling Point:521.9°Cat760mmHg
Flash Point:243.6°C
Density:1.344g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 10-(chloromethyl)benzo[pqr]tetraphene

There total 16 articles about 10-(chloromethyl)benzo[pqr]tetraphene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 86803-18-1
10-(hydroxymethyl)benzo pyrene

: 86803-19-2
10-(chloromethyl)benzo pyrene

Guidance literature:: With thionyl chloride; In benzene; for 15h; Ambient temperature;
DOI:10.1021/jo00168a048

Reference yield:

: 64709-55-3
1-pyreneacetic acid

: 86803-19-2
10-(chloromethyl)benzo pyrene

Guidance literature:: Multi-step reaction with 8 steps

1: H₂SO₄ / benzene

2: 75 percent / NaOEt / ethanol / 18 h / Heating

3: 74 percent / KOH / ethanol / 24 h / Heating

4: 71 percent / anhydr. HF

5: 80 percent / Zn(Hg), conc. HCl / H₂O; toluene / 24 h / Heating

6: 65 percent / DDQ / benzene / 24 h / Heating

7: 95 percent / LiAlH₄ / diethyl ether / 1.) 35 min, reflux, 2.) room temp., overnight

8: 71 percent / SOCl₂ / benzene / 15 h / Ambient temperature

With hydrogenchloride; potassium hydroxide; lithium aluminium tetrahydride; thionyl chloride; sulfuric acid; hydrogen fluoride; sodium ethanolate; mercury; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In diethyl ether; ethanol; water; toluene; benzene;
DOI:10.1021/jo00168a048

Reference yield:

: 86803-13-6
ethyl α-(1-pyrenyl)glutarate

: 86803-19-2
10-(chloromethyl)benzo pyrene

Guidance literature:: Multi-step reaction with 6 steps

1: 74 percent / KOH / ethanol / 24 h / Heating

2: 71 percent / anhydr. HF

3: 80 percent / Zn(Hg), conc. HCl / H₂O; toluene / 24 h / Heating

4: 65 percent / DDQ / benzene / 24 h / Heating

5: 95 percent / LiAlH₄ / diethyl ether / 1.) 35 min, reflux, 2.) room temp., overnight

6: 71 percent / SOCl₂ / benzene / 15 h / Ambient temperature

With hydrogenchloride; potassium hydroxide; lithium aluminium tetrahydride; thionyl chloride; hydrogen fluoride; mercury; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In diethyl ether; ethanol; water; toluene; benzene;
DOI:10.1021/jo00168a048