3-Cyclohexene-1-acetaldehyde, 2,2,3-trimethyl-, (R)-

Base Information

Chemical Name:3-Cyclohexene-1-acetaldehyde, 2,2,3-trimethyl-, (R)-
CAS No.:144342-35-8
Molecular Formula:C11H18O
Molecular Weight:166.263
Hs Code.:
Mol file:144342-35-8.mol

Synonyms:

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Chemical Property of 3-Cyclohexene-1-acetaldehyde, 2,2,3-trimethyl-, (R)-

Chemical Property:

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Technology Process of 3-Cyclohexene-1-acetaldehyde, 2,2,3-trimethyl-, (R)-

There total 11 articles about 3-Cyclohexene-1-acetaldehyde, 2,2,3-trimethyl-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 144342-42-7
(-)-(1R)-2,2,3-Trimethylcyclohex-3-ene-1-ethanol

: 144342-35-8
(-)-(1R)-2,2,3-Trimethylcyclohex-3-ene-1-acetaldehyde

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; Ambient temperature;
DOI:10.1002/hlca.19920750507

Reference yield: 65.0%

: (+)-(1'R)-2-(6',6'-dimethyl-5'-oxo-3'-cyclohexen-1'-yl)ethyl acetate

: 144342-35-8
(-)-(1R)-2,2,3-Trimethylcyclohex-3-ene-1-acetaldehyde

Guidance literature:

Reference yield:

: 7785-26-4,25766-18-1
(-)-α-pinene

: 144342-35-8
(-)-(1R)-2,2,3-Trimethylcyclohex-3-ene-1-acetaldehyde

Guidance literature:: Multi-step reaction with 10 steps

1: 78 percent / 40 percent peracetic acid/AcOH, Na₂CO₃, EDTA tetrasodium salt / toluene / Ambient temperature

2: 75 percent / ZnBr₂ / toluene / Heating

3: 97 percent / LiAlH₄ / diethyl ether / 1.) reflux, 2.) r.t., 1 h

4: 87 percent / conc. H₃PO₄ / 2 h / 60 °C

6: 95 percent / hydrogen / Raney-Ni / ethanol / 8 h / Ambient temperature

7: 72 percent / t-BuOK / toluene / 3 h / Heating

8: 70 percent / TsOH / toluene / 2 h / Heating

9: 95 percent / LiAlH₄ / diethyl ether / 1 h / Ambient temperature

10: 92 percent / pyridinium chlorochromate / CH₂Cl₂ / Ambient temperature

With peracetic acid; lithium aluminium tetrahydride; phosphoric acid; potassium tert-butylate; hydrogen; ethylene diamine tetraacetic acid tetrasodium salt; sodium carbonate; toluene-4-sulfonic acid; acetic acid; pyridinium chlorochromate; zinc dibromide; nickel; In diethyl ether; ethanol; dichloromethane; toluene;
DOI:10.1002/hlca.19920750507