Magnesium, chloro[(2-chlorophenyl)methyl]-

Base Information

Chemical Name:Magnesium, chloro[(2-chlorophenyl)methyl]-
CAS No.:29874-00-8
Molecular Formula:C7H6 Cl2 Mg
Molecular Weight:185.336
Hs Code.:
DSSTox Substance ID:DTXSID8067523
Mol file:29874-00-8.mol

Synonyms:29874-00-8;Magnesium, chloro[(2-chlorophenyl)methyl]-;2-chlorobenzylmagnesium chloride;magnesium;1-chloro-2-methanidylbenzene;chloride;Chloro[(2-chlorophenyl)methyl]magnesium;Magnesium, chloro((2-chlorophenyl)methyl)-;MFCD01319895;o-Chlorobenzylmagnesium chloride;SCHEMBL187563;DTXSID8067523;WDNZKGYAWFIMJL-UHFFFAOYSA-M;(2-Chlorobenzyl)magnesium chloride;AKOS016017760;2-Chlorobenzylmagnesium chloride, 0.50 M in Ether;2-Chlorobenzylmagnesium chloride, 0.50 M in 2-MeTHF;2-Chlorobenzylmagnesium chloride 0.25 M in Diethyl Ether

Suppliers and Price of Magnesium, chloro[(2-chlorophenyl)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
2-Chlorobenzylmagnesiumchloride
250ml
$ 498.00

Rieke Metals
2-Chlorobenzylmagnesiumchloride
100mL
$ 312.00

Rieke Metals
2-Chlorobenzylmagnesiumchloride
100mL
$ 311.00

Rieke Metals
2-Chlorobenzylmagnesiumchloride
50mL
$ 238.00

Matrix Scientific
2-Chlorobenzylmagnesiumchloride 0.50Min2-MeTHF97%
100ml
$ 615.00

American Custom Chemicals Corporation
2-CHLOROBENZYLMAGNESIUM CHLORIDE 95.00%
100ML
$ 2783.55

Alfa Aesar
2-Chlorobenzylmagnesium chloride, 0.50M in 2-MeTHF
100ml
$ 256.00

Total 5 raw suppliers

Chemical Property of Magnesium, chloro[(2-chlorophenyl)methyl]-

Chemical Property:

Vapor Pressure:3.77mmHg at 25°C
Boiling Point:156.2°Cat760mmHg
Flash Point:47.2°C
PSA：0.00000
Density:g/cm³
LogP:-0.55660
Sensitive.:Air & Moisture Sensitive
Water Solubility.:Reacts with water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:183.9696973
Heavy Atom Count:10
Complexity:78

Purity/Quality:

97% ^*data from raw suppliers

2-Chlorobenzylmagnesiumchloride ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[CH2-]C1=CC=CC=C1Cl.[Mg+2].[Cl-]
Uses It is used as pharmaceutical intermediate.

Technology Process of Magnesium, chloro[(2-chlorophenyl)methyl]-

There total 1 articles about Magnesium, chloro[(2-chlorophenyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.5%

: 611-19-8
1-chloro-2-(chloromethyl)benzene

: 29874-00-8
(2-chlorobenzyl)magnesium chloride

Guidance literature:: 1-chloro-2-(chloromethyl)benzene; With magnesium; ethylene dibromide; In dibutyl ether; at 20 - 30 ℃; for 0.166667h; Inert atmosphere;

1-chloro-2-(chloromethyl)benzene; In dibutyl ether; cyclohexane; at -5 - 5 ℃; for 4h; Solvent; Temperature;

Reference yield: 65.7%

: N-methoxy-N,3,4-trimethylisoxazole-5-carboxamide

: 29874-00-8
(2-chlorobenzyl)magnesium chloride

: 2-(2-chlorophenyl)-1-(3,4-dimethylisoxazol-5-yl)ethanone

Guidance literature:: In tetrahydrofuran; 2-methyltetrahydrofuran; at -78 - 20 ℃; for 17h; Inert atmosphere;

Reference yield: 26.0%

: 14044-65-6
borane-THF

: 6-(?)-menthyl-6H-dibenzo[c,e][1,2]oxaphosphinine

: 29874-00-8
(2-chlorobenzyl)magnesium chloride

: C₂₉H₃₇BClOP

Guidance literature:: 6-(?)-menthyl-6H-dibenzo[c,e][1,2]oxaphosphinine; (2-chlorobenzyl)magnesium chloride; In tetrahydrofuran; diethyl ether; at 80 ℃; for 8h; Cooling with ice;

borane-THF; In tetrahydrofuran; at 20 ℃; for 2h;
DOI:10.1021/acs.joc.9b00346