Silane, (5-bromo-1-oxopentyl)methyldiphenyl-

Base Information

Chemical Name:Silane, (5-bromo-1-oxopentyl)methyldiphenyl-
CAS No.:144692-56-8
Molecular Formula:C18H21BrOSi
Molecular Weight:361.354
Hs Code.:
DSSTox Substance ID:DTXSID90451082
Nikkaji Number:J513.836A

Synonyms:Silane, (5-bromo-1-oxopentyl)methyldiphenyl-;144692-56-8;DTXSID90451082;1-(Methyldiphenylsilyl)-5-bromo-1-pentanone

Suppliers and Price of Silane, (5-bromo-1-oxopentyl)methyldiphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Silane, (5-bromo-1-oxopentyl)methyldiphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:7
Exact Mass:360.05450
Heavy Atom Count:21
Complexity:301

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(=O)CCCCBr

Technology Process of Silane, (5-bromo-1-oxopentyl)methyldiphenyl-

There total 4 articles about Silane, (5-bromo-1-oxopentyl)methyldiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 144-79-6
chloromethyldiphenylsilane

: 144692-56-8
5-Bromo-1-(methyl-diphenyl-silanyl)-pentan-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / n-BuLi / tetrahydrofuran; hexane / 1.) 0 deg C, 20 min, 2.) 0 deg C, 10 min; room temperature, 30 min

2: 1.) n-BuLi, 2.) red HgO, Celite, BF₃*Et₂O / 1.) THF, hexane, 0 deg C, 30 min; -30 deg C, 1.5 h, 2.) THF, H₂O, room temperature, 1 h

With n-butyllithium; Celite; boron trifluoride diethyl etherate; mercury(II) oxide; In tetrahydrofuran; hexane;
DOI:10.1021/jo9711302

Reference yield:

: 135746-48-4
[2-(4-Bromo-butyl)-[1,3]dithian-2-yl]-methyl-diphenyl-silane

: 144692-56-8
5-Bromo-1-(methyl-diphenyl-silanyl)-pentan-1-one

Guidance literature:: With Celite; boron trifluoride diethyl etherate; mercury(II) oxide; In tetrahydrofuran; water; Yield given;
DOI:10.1016/0040-4039(91)80820-V

Reference yield:

: 135746-47-3
2-methyldiphenylsilyl-1,3-dithiane

: 144692-56-8
5-Bromo-1-(methyl-diphenyl-silanyl)-pentan-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: BuLi / tetrahydrofuran

2: HgO, BF₃*OEt, Celite / tetrahydrofuran; H₂O

With n-butyllithium; Celite; boron trifluoride diethyl etherate; mercury(II) oxide; In tetrahydrofuran; water;
DOI:10.1016/0040-4039(91)80820-V