Benzo[c]picene

Base Information

• Chemical Name: Benzo[c]picene
• CAS No.: 217-37-8
• Molecular Formula: C26H16
• Molecular Weight: 328.413
• Hs Code.: 2902909090
• European Community (EC) Number: 205-921-3
• DSSTox Substance ID: DTXSID10176083
• Nikkaji Number: J193.679D
• Wikidata: Q55830219
• Mol file: 217-37-8.mol

Synonyms:Benzo[c]picene;BENZO(C)PICENE;217-37-8;DTXSID10176083;EINECS 205-921-3;T70489

Chemical Property of Benzo[c]picene

Chemical Property:

• Vapor Pressure: 6.64E-14mmHg at 25°C
• Boiling Point: 604.1°Cat760mmHg
• Flash Point: 314.6°C
• PSA: 0.00000
• Density: 1.263g/cm³
• LogP: 7.45260
• XLogP3: 8.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 328.125200510
• Heavy Atom Count: 26
• Complexity: 462

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C=CC4=C3C=CC5=C4C=CC6=CC=CC=C65

Technology Process of Benzo[c]picene

There total 23 articles about Benzo[c]picene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1-(1-naphthyl)-2-(1-phenanthryl)ethane → benzo[c]picene (217-37-8)

Guidance literature:

With iodine; In toluene; for 0.1h; Time; Irradiation;

DOI:10.1246/cl.140182

Reference yield: 35.0%

C26H18Cl2 → benzo[c]picene (217-37-8)

Guidance literature:

With caesium carbonate; tricyclohexylphosphine; Trimethylacetic acid; at 20 - 150 ℃; for 20h; Schlenk technique; Inert atmosphere;

DOI:10.1246/cl.130584

Reference yield: 7.5%

1-(1-naphthyl)-2-(1-phenanthryl)ethane (1423072-72-3) → benzo[c]picene (217-37-8)

Guidance literature:

With 9-fluorenone; In chloroform; for 72h; Inert atmosphere; Photolysis;

DOI:10.1007/s11164-012-0639-1

upstream raw materials:

1-allylnaphthalene

C₂₆H₃₂O₂

1,5-Divinylnaphthalene

1,5-dibromonaphthalene

Refernces

• 1、 Okamoto, Hideki,Takahashi, Haruhiko,Takane, Takamitsu,Nishiyama, Yasuhiro,Kakiuchi, Kiyomi,Gohda, Shin,Yamaji, Minoru. "Convenient Phenacene Synthesis by Sequentially Performed Wittig Reaction and Mallory Photocyclization Using Continuous-Flow Techniques". . p. 2949 - 2957. Retrieved 2017/06/27.
• 2、 Chang, Ning-Hui,Mori, Hiroki,Chen, Xi-Chao,Okuda, Yasuhiro,Okamoto, Takeru,Nishihara, Yasushi. "Synthesis of substituted [6]phenacenes through Suzuki-Miyaura coupling of polyhalobenzene with alkenylboronates and sequential intramolecular cyclization via C-H bond activation". . p. 1257 - 1259. Retrieved 2013/10/22.