1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)-

Base Information

• Chemical Name: 1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)-
• CAS No.: 15419-92-8
• Molecular Formula: C16H12N2O2
• Molecular Weight: 264.283
• DSSTox Substance ID: DTXSID50434250
• Nikkaji Number: J1.994.505G
• Mol file: 15419-92-8.mol

Synonyms:15419-92-8;1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)-;SCHEMBL16095556;SCHEMBL16095557;DTXSID50434250;STL257050;AKOS015995653;N,N'-Difurfurylidene-1,2-phenylenediamine;N,N'-bis[(E)-furan-2-ylmethylidene]benzene-1,2-diamine

Chemical Property of 1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)-

Chemical Property:

• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 264.089877630
• Heavy Atom Count: 20
• Complexity: 322

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)N=CC2=CC=CO2)N=CC3=CC=CO3

Technology Process of 1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)-

There total 4 articles about 1,2-Benzenediamine, N,N'-bis(2-furanylmethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

furfural (98-01-1) + 1,2-diamino-benzene (95-54-5) → fur-o-phdn (15419-92-8) + fuberidazole (3878-19-1) + 2-(2-furyl)-1-(2-furylmethyl)benzimidazole (79324-83-7)

Guidance literature:

With γ-maghemite-silica nanocomposite from 50-150 mg FeCl3/g silica activated; In neat (no solvent); Green chemistry;

DOI:10.1016/j.catcom.2013.06.026

Reference yield:

furfural (98-01-1) + 1,2-diamino-benzene (95-54-5) → fur-o-phdn (15419-92-8)

Guidance literature:

With γ-maghemite-silica nanocomposite from 20 mg FeCl3/g silica activated; In neat (no solvent); Green chemistry;

DOI:10.1016/j.catcom.2013.06.026

Reference yield:

furfural (98-01-1) + 1,2-diamino-benzene (95-54-5) → N,N'-bis(furylidene)-o-phenylenediamine (15419-92-8)

Guidance literature:

In methanol; for 2h; Ambient temperature;

DOI:10.1021/jo00114a013

upstream raw materials:

furfural

1,2-diamino-benzene

Downstream raw materials:

2,3-di-furan-2-yl-quinoxaline

Refernces

• 1、 Ghosh, Pranab,Mandal, Amitava,Subba, Raju. "γ-Maghemite-silica nanocomposite: A green catalyst for diverse aromatic N-heterocycles". . p. 146 - 152. Retrieved 2013/09/02.
• 2、 Reich, B. Jesse E.,Justice, Aaron K.,Beckstead, Brittany T.,Reibenspies, Joseph H.,Miller, Stephen A.. "Cyanide-Catalyzed Cyclizations via Aldimine Coupling". . p. 1357 - 1359. Retrieved 2007/10/03.