Stannane, tributyl[phenyl(phenylthio)methyl]-

Base Information

Chemical Name:Stannane, tributyl[phenyl(phenylthio)methyl]-
CAS No.:155127-04-1
Molecular Formula:C25H38SSn
Molecular Weight:489.353
Hs Code.:
Mol file:155127-04-1.mol

Synonyms:

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Chemical Property of Stannane, tributyl[phenyl(phenylthio)methyl]-

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Technology Process of Stannane, tributyl[phenyl(phenylthio)methyl]-

There total 1 articles about Stannane, tributyl[phenyl(phenylthio)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 831-91-4
Benzyl phenyl sulfide

: 1461-22-9
tributyltin chloride

: 155127-04-1
1-phenyl-1-(phenylthio)-1-(tributylstannyl)methane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; BuLi in hexane was added dropwise to benzyl phenyl sulfide in THF (-78°C) under Ar, stirred (30 min, 0 °C) and cooled again to -78 °C; then ClSn(n-Bu)3 was added, the mixt. stirred overnight and allowed to warm up to room temp.;; the react. was quenched with water, after filtration over celite and washing the celite with hexane, the org. phase was separated, the aq. phase extracted with hexane, the extracts dried over Na2SO4, the solvent removed in vac.; chromy. on silica gel;;
DOI:10.1246/bcsj.66.2995

Reference yield: 100.0%

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 155127-04-1
1-phenyl-1-(phenylthio)-1-(tributylstannyl)methane

: (S)-1-[1-phenyl-1-(phenylthio)methyl]-1-cyclohexanol

Guidance literature:: 1-phenyl-1-(phenylthio)-1-(tributylstannyl)methane; With n-butyllithium; at -78 ℃; for 0.166667h;

cyclohexanone; With 2,2-bis[(4S)-4-isopropyloxazolin-2-yl]propane; In hexane; at -78 ℃; for 1h;
DOI:10.1002/(SICI)1521-3773(20000117)39:2<353::AID-ANIE353>3.0.CO;2-1