12-Methacryloyldodeylphosphate

Base Information

• Chemical Name: 12-Methacryloyldodeylphosphate
• CAS No.: 85590-00-7
• Molecular Formula: C14H27O6P
• Molecular Weight: 322.339
• Hs Code.: 2931900090
• Mol file: 85590-00-7.mol

Synonyms:Methacryloyloxydecyl dihydrogen phosphate;MADDP;Cesead opaque primer;10-(Phosphonooxy)decyl 2-methylprop-2-enoate;New Panavia TPN-S;2-Propenoic acid,2-methyl-,esters,10- (phosphonooxy)decyl ester;

Chemical Property of 12-Methacryloyldodeylphosphate

Chemical Property:

• Vapor Pressure: 2.33E-09mmHg at 25°C
• Refractive Index: 1.475
• Boiling Point: 450.2 °C at 760 mmHg
• PKA: 1.95±0.10(Predicted)
• Flash Point: 226.1 °C
• PSA: 102.87000
• Density: 1.136 g/cm³
• LogP: 3.33580
• Storage Temp.: 2-8°C
• Solubility.: Acetonitrile (Slightly, Heated, Sonicated), Aqueous Base (Very Slightly), DMSO (

Purity/Quality:

95%min ^*data from raw suppliers

10-Methacryloyldecylphosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 10MDP/12-Methacryloyldodeylphosphate is a compound used in dentistry. It is used to formulate a bonding agent consisting of calcium phosphate powder mixed with adhesive monomer used in pulp capping.

Technology Process of 12-Methacryloyldodeylphosphate

There total 4 articles about 12-Methacryloyldodeylphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

methacryloyloxydecyl dimethoxy phosphate → 10-methacryloyloxydecyl dihydrogen phosphate (85590-00-7)

Guidance literature:

With trimethylsilyl bromide; at 20 ℃; for 26h; Time; Inert atmosphere;

Reference yield:

10-hydroxydecyl methacrylate (56927-66-3) → 10-methacryloyloxydecyl dihydrogen phosphate (85590-00-7)

Guidance literature:

10-hydroxydecyl methacrylate; With triethylamine; trichlorophosphate; In tetrahydrofuran; at -40 ℃; for 3h;

With water; In tetrahydrofuran; at -40 ℃; for 0.25h;

Reference yield:

1,10-Decanediol (112-47-0) → 10-methacryloyloxydecyl dihydrogen phosphate (85590-00-7)

Guidance literature:

Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / 10 h / 85 °C

2: carbon tetrabromide; pyridine / 7 h / 20 °C / Cooling with ice; Inert atmosphere

3: trimethylsilyl bromide / 26 h / 20 °C / Inert atmosphere

With pyridine; trimethylsilyl bromide; carbon tetrabromide; toluene-4-sulfonic acid;

upstream raw materials:

10-hydroxydecyl methacrylate

1,10-Decanediol

Downstream raw materials:

acetone

Refernces

• 1、 -. "PRODUCTION METHOD OF PHOSPHORIC ACID ESTER-BASED METHACRYL MONOMER FOR DENTISTRY". Paragraph 0063-0067. . Retrieved 2021/06/11.
• 2、 -. "Oral adhesive methacryloyl decyl dihydro phosphorus acid ester synthetic method". . . Retrieved 2017/03/08.