1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-

Base Information

Chemical Name:1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-
CAS No.:159087-53-3
Molecular Formula:C16H23BO2
Molecular Weight:258.168
Hs Code.:
DSSTox Substance ID:DTXSID40472404
Nikkaji Number:J618.803F
Wikidata:Q82301330
Mol file:159087-53-3.mol

Synonyms:2057416-43-8;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-;159087-53-3;DTXSID40472404;1,3,2-Dioxaborolane,4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-;4,4,5,5-Tetramethyl-2-[(1Z)-4-phenylbut-1-en-1-yl]-1,3,2-dioxaborolane

Suppliers and Price of 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:258.1791101
Heavy Atom Count:19
Complexity:301

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C=CCCC2=CC=CC=C2
Isomeric SMILES:B1(OC(C(O1)(C)C)(C)C)/C=C\CCC2=CC=CC=C2

Technology Process of 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]-

There total 8 articles about 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1Z)-4-phenyl-1-buten-1-yl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 16520-62-0
4-Phenyl-1-butyne

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 159087-53-3
(Z)-4,4,5,5-tetramethyl-2-(4-phenylbut-1-en-1-yl)-1,3,2-dioxaborolane

Guidance literature:: With (^CyAPDI)CoCH₃; In tetrahydrofuran; at 23 ℃; for 6h; stereoselective reaction; Glovebox;
DOI:10.1021/jacs.5b00936

Reference yield: 64.0%

: 218902-81-9
(Z)-(4-iodobut-3-en-1-yl)benzene

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 159087-53-3
(Z)-4,4,5,5-tetramethyl-2-(4-phenylbut-1-en-1-yl)-1,3,2-dioxaborolane

Guidance literature:: dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; With sodium ethanolate; In 1,2-dimethoxyethane; at 30 ℃; for 0.166667h;

(Z)-(4-iodobut-3-en-1-yl)benzene; In 1,2-dimethoxyethane; at 30 ℃; for 1h;
DOI:10.1039/c5sc00384a

Reference yield: 51.8%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 16520-62-0
4-Phenyl-1-butyne

: 274-07-7
benzo[1,3,2]dioxaborole

: 159087-53-3
(Z)-4,4,5,5-tetramethyl-2-(4-phenylbut-1-en-1-yl)-1,3,2-dioxaborolane

Guidance literature:: 4-Phenyl-1-butyne; benzo[1,3,2]dioxaborole; With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triethylamine; tris(1-methylethyl)phosphine; In cyclohexane; at 22 ℃; for 3.5h; Inert atmosphere;

2,3-dimethyl-2,3-butane diol; In cyclohexane; at 22 ℃; for 13h; Inert atmosphere;
DOI:10.1021/acs.orglett.0c00412