L-ANTI-ENDO-3,4-METHANOPYRROLIDINEDICARBOXYLIC ACID

Base Information

• Chemical Name: L-ANTI-ENDO-3,4-METHANOPYRROLIDINEDICARBOXYLIC ACID
• CAS No.: 159262-32-5
• Molecular Formula: C7H9NO4
• Molecular Weight: 171.15100
• Mol file: 159262-32-5.mol

Synonyms:3-Azabicyclo[3.1.0]hexane-2,6-dicarboxylic acid, (1R,2S,5S,6S)-;3-Azabicyclo[3.1.0]hexane-2,6-dicarboxylic acid, [1R-(1α,2α,5α,6β)]-;(1R,2S,5S,6S)-3-Azabicyclo[3.1.0]hexane-2,6-dicarboxylic acid;

Chemical Property of L-ANTI-ENDO-3,4-METHANOPYRROLIDINEDICARBOXYLIC ACID

Chemical Property:

• Boiling Point: 381.2±42.0 °C(Predicted)
• PKA: 2.14±0.40(Predicted)
• PSA: 86.63000
• Density: 1.584±0.06 g/cm3(Predicted)
• LogP: -0.68160
• Storage Temp.: Store at RT

Purity/Quality:

97% ^*data from raw suppliers

MPDC ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: MPDC is a potent inhibitor of L-glutamate uptake and may be useful in the treatment of neurodegeneration.

Technology Process of L-ANTI-ENDO-3,4-METHANOPYRROLIDINEDICARBOXYLIC ACID

There total 8 articles about L-ANTI-ENDO-3,4-METHANOPYRROLIDINEDICARBOXYLIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(1R,2S,5S,6R)-3-Aza-bicyclo[3.1.0]hexane-2,3,6-tricarboxylic acid 3-benzyl ester 6-ethyl ester 2-methyl ester → (2S,3R,4S,6R) 6-Carboxy-3,4-methanoproline (159262-32-5)

Guidance literature:

With hydrogenchloride; for 3h; Heating;

Reference yield: 90.0%

(1R,2S,5S,6S)-3-Aza-bicyclo[3.1.0]hexane-2,3,6-tricarboxylic acid 3-benzyl ester 6-ethyl ester 2-methyl ester → (2S,3R,4S,6S) 6-Carboxy-3,4-methanoproline (159262-32-5)

Guidance literature:

With hydrogenchloride; for 3h; Heating;

Reference yield: 75.0%

(1S,2R,5R,6S)-3-Aza-bicyclo[3.1.0]hexane-2,3,6-tricarboxylic acid 3-benzyl ester 6-ethyl ester 2-methyl ester → (2R,3S,4R,6S) 6-Carboxy-3,4-methanoproline (159262-32-5)

Guidance literature:

With hydrogenchloride; for 4h; Heating;

upstream raw materials:

(2S)-2,5-dihydro-1H-pyrrole-1,2-dicarboxylic acid 2-methyl 1-(phenylmethyl) ester

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