1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione

Base Information

Chemical Name:1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione
CAS No.:15939-83-0
Molecular Formula:C26H18N2O4
Molecular Weight:422.44
Hs Code.:
DSSTox Substance ID:DTXSID60594238
Wikidata:Q82489023
Mol file:15939-83-0.mol

Synonyms:15939-83-0;1,4-Bis((4-hydroxyphenyl)amino)anthracene-9,10-dione;SCHEMBL5271808;DTXSID60594238;1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione

Suppliers and Price of 1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione

Chemical Property:

XLogP3:6.3
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:4
Exact Mass:422.12665706
Heavy Atom Count:32
Complexity:625

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C(=O)C3=C(C=CC(=C3C2=O)NC4=CC=C(C=C4)O)NC5=CC=C(C=C5)O

Technology Process of 1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione

There total 4 articles about 1,4-Bis(4-hydroxyanilino)anthracene-9,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 602-25-5
1,4-dichloroanthraquinone

: 123-30-8
4-amino-phenol

: 15939-83-0
1,4-bis(4-hydroxyphenylamino)anthraquinone

Guidance literature:: With disodium hydrogenphosphate; In 1-methyl-pyrrolidin-2-one; at 150 - 180 ℃; for 15h; Inert atmosphere;
DOI:10.3762/bjoc.9.48

Reference yield:

: 2905-61-5
2,5-dichlorobenzoyl chloride

: 15939-83-0
1,4-bis(4-hydroxyphenylamino)anthraquinone

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / 4 h / 150 °C

2: disodium hydrogenphosphate / 1-methyl-pyrrolidin-2-one / 15 h / 150 - 180 °C / Inert atmosphere

With disodium hydrogenphosphate; sulfuric acid; In 1-methyl-pyrrolidin-2-one;
DOI:10.3762/bjoc.9.48

Reference yield:

: 106-46-7,84348-21-0
para-dichlorobenzene

: 15939-83-0
1,4-bis(4-hydroxyphenylamino)anthraquinone

Guidance literature:: Multi-step reaction with 3 steps

1: phthalic anhydride; aluminum (III) chloride; sodium chloride / 6 h / 115 °C

2: sulfuric acid / 4 h / 150 °C

3: disodium hydrogenphosphate / 1-methyl-pyrrolidin-2-one / 15 h / 150 - 180 °C / Inert atmosphere

With aluminum (III) chloride; disodium hydrogenphosphate; phthalic anhydride; sulfuric acid; sodium chloride; In 1-methyl-pyrrolidin-2-one; 1: |Friedel-Crafts Acylation;
DOI:10.3762/bjoc.9.48