Technology Process of (3S,6aS,9S,10R,10aR)-4-formyl-3,10-dihydroxy-7,7-dimethyl-1-oxo-3,3a,6,6a,7,8,9,10-octahydronaphtho[1,8a-c]furan-9-yl 2-(acetyloxy)decanoate
There total 9 articles about (3S,6aS,9S,10R,10aR)-4-formyl-3,10-dihydroxy-7,7-dimethyl-1-oxo-3,3a,6,6a,7,8,9,10-octahydronaphtho[1,8a-c]furan-9-yl 2-(acetyloxy)decanoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: osmium(VIII) oxide / tetrahydrofuran; water
2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0 - 20 °C
3: pyridinium p-toluenesulfonate / water; acetone
With
dmap; osmium(VIII) oxide; pyridinium p-toluenesulfonate; dicyclohexyl-carbodiimide;
In
tetrahydrofuran; dichloromethane; water; acetone;
2: |Steglich Esterification;
DOI:10.1055/s-0033-1339172
- Guidance literature:
-
Multi-step reaction with 6 steps
1: AD-mix β / tert-butyl alcohol; water
2: pyridine
3: hydrogenchloride / tetrahydrofuran
4: ruthenium trichloride; sodium periodate
5: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0 - 20 °C
6: pyridinium p-toluenesulfonate / water; acetone
With
pyridine; hydrogenchloride; dmap; ruthenium trichloride; sodium periodate; AD-mix β; pyridinium p-toluenesulfonate; dicyclohexyl-carbodiimide;
In
tetrahydrofuran; dichloromethane; water; acetone; tert-butyl alcohol;
1: |Sharpless Asymmetric Epoxidation / 5: |Steglich Esterification;
DOI:10.1055/s-0033-1339172