Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-

Base Information

Chemical Name:Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-
CAS No.:161512-00-1
Molecular Formula:C10H10O2
Molecular Weight:162.188
Hs Code.:
DSSTox Substance ID:DTXSID10438133
Nikkaji Number:J591.929K
Wikidata:Q82253771
Mol file:161512-00-1.mol

Synonyms:Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-;161512-00-1;SCHEMBL5194624;DTXSID10438133;2alpha-Benzoyl-3beta-methyloxirane

Suppliers and Price of Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:162.068079557
Heavy Atom Count:12
Complexity:182

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C(O1)C(=O)C2=CC=CC=C2
Isomeric SMILES:C[C@@H]1[C@H](O1)C(=O)C2=CC=CC=C2

Technology Process of Methanone, [(2S,3R)-3-methyloxiranyl]phenyl-

There total 4 articles about Methanone, [(2S,3R)-3-methyloxiranyl]phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 154902-01-9
(R,R,R)-(-)-erythro-trans-1-phenyl-2,3-epoxybutan-1-ol

: 161512-00-1
(2S,3R)-trans-epoxy-3-methyl-1-phenylpropan-1-one

Guidance literature:: With dipyridinium dichromate;

Reference yield:

: 35660-91-4,35845-66-0,495-41-0
(E)-1-phenyl-2-buten-1-one

: 161512-01-2
(2R,3S)-trans-epoxy-3-methyl-1-phenylpropan-1-one

: 161512-00-1
(2S,3R)-trans-epoxy-3-methyl-1-phenylpropan-1-one

Guidance literature:: With (1R,2R)-pseudoephedrine; diethylzinc; oxygen; In toluene; Yield given. Yields of byproduct given. Title compound not separated from byproducts; 1.) -78 deg C, 30 min, 2.) 0 deg C, 3.5 h;

Reference yield:

: 495-41-0
1-phenylbut-2-en-1-one

: 161512-01-2
(2R,3S)-trans-epoxy-3-methyl-1-phenylpropan-1-one

: 161512-00-1
(2S,3R)-trans-epoxy-3-methyl-1-phenylpropan-1-one

Guidance literature:: With C₅₇H₅₅N; dihydrogen peroxide; In water; toluene; at 20 ℃; for 14h; optical yield given as %ee; enantioselective reaction;
DOI:10.3987/COM-08-S(N)105