azane, (1,1-dimethylethyl)[(1,1-dimethylethyl)azanylidene]oxido-

Base Information

• Chemical Name: azane, (1,1-dimethylethyl)[(1,1-dimethylethyl)azanylidene]oxido-
• CAS No.: 16649-52-8
• Molecular Formula: C₈H₁₈N₂O
• Molecular Weight: 158.244
• Mol file: 16649-52-8.mol

Synonyms:

Chemical Property of azane, (1,1-dimethylethyl)[(1,1-dimethylethyl)azanylidene]oxido-

Chemical Property:

• Vapor Pressure: 0.404mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of azane, (1,1-dimethylethyl)[(1,1-dimethylethyl)azanylidene]oxido-

There total 6 articles about azane, (1,1-dimethylethyl)[(1,1-dimethylethyl)azanylidene]oxido- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

t-butylnitrite (917-95-3) → benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + 2,2'-dimethyl-2,2'-azoxypropane (16649-52-8,54168-23-9,87339-11-5)

Guidance literature:

In tetrahydrofuran; for 6h; Heating;

DOI:10.1016/0022-328X(89)80121-4

Reference yield: 66.0%

t-butylnitrite (917-95-3) + pentacarbonyl(1-methoxybenzylidene)chromium(0) (27436-93-7) → benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + di-t-butyldiazene N-oxide (16649-52-8,54168-23-9,87339-11-5)

Guidance literature:

In tetrahydrofuran; Soln. of 2-nitroso-2-methylpropane in THF is stirred at 25°C until it is dark blue, a soln. of carbene complex in THF is added, the soln. is then refluxed for 6 h, cooling to 25°C.; naphthalene and biphenyl as internal standards, GC-MS anal.;

DOI:10.1016/0022-328X(89)80121-4

Reference yield: 35.0%

pentacarbonyl(methoxyphenylmethylene)tungsten(0) (37823-96-4) + t-butylnitrite (917-95-3) → benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + W(CO)5(t-BuNO) (116301-27-0) + di-t-butyldiazene N-oxide (16649-52-8,54168-23-9,87339-11-5)

Guidance literature:

In chloroform-d1; N2 atmosphere; addn. of soln. of W-compd. in CDCl3 to org. compd.; chromy. (SiO2); (1)H-NMR monitoring (5 d);

upstream raw materials:

t-butylnitrite

iron pentacarbonyl

pentacarbonyl(methoxyphenylmethylene)tungsten⁽⁰⁾

pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾

Downstream raw materials:

Di-tert-butyl-oxadiaziridin

Refernces

• 1、 Herndon, James W.,McMullen, Leonard A.. "Metathesis and reduction reactions of nitroso compounds with metal carbenes and metal carbonyls". . p. 83 - 102. Retrieved 2007/10/02.