Bromohexyltriphenylphosphorane

Base Information

• Chemical Name: Bromohexyltriphenylphosphorane
• CAS No.: 39521-32-9
• Molecular Formula: C24H27BrP+
• Molecular Weight: 427.364
• Hs Code.: 2931900090
• European Community (EC) Number: 254-491-3
• DSSTox Substance ID: DTXSID70960142
• Nikkaji Number: J715.419D
• Wikidata: Q82941202
• Mol file: 39521-32-9.mol

Synonyms:Bromohexyltriphenylphosphorane;39521-32-9;EINECS 254-491-3;SCHEMBL25330102;DTXSID70960142;(6-Bromohexyl)(triphenyl)phosphanium

Chemical Property of Bromohexyltriphenylphosphorane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 5.93580
• XLogP3: 6.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 425.10338
• Heavy Atom Count: 26
• Complexity: 319

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[P+](CCCCCCBr)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Bromohexyltriphenylphosphorane

There total 1 articles about Bromohexyltriphenylphosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

1-bromo-hexane (111-25-1) + triphenylphosphine (603-35-0) → (hexyl)(triphenyl)phosphonium bromide (39521-32-9)

Guidance literature:

In toluene; at 100 ℃; for 48h; Inert atmosphere;

DOI:10.1021/acs.joc.7b00376

Reference yield: 65.0%

(hexyl)(triphenyl)phosphonium bromide (39521-32-9) + 5-oxo-pentadecanal (86648-94-4) → (Z)-6-heneicosen-11-one (54844-65-4)

Guidance literature:

Reference yield: 65.0%

4-oxopentanal (626-96-0) + (hexyl)(triphenyl)phosphonium bromide (39521-32-9) → (Z)-undec-5-en-2-one (21944-96-7,40657-56-5)

Guidance literature:

sodium hexamethyldisilazane;

DOI:10.1007/BF00574612

upstream raw materials:

1-bromo-hexane

triphenylphosphine

Downstream raw materials:

(Z)-undec-5-en-2-one

(Z)-6-heneicosen-11-one

(R)-2-((Z)-Hept-1-enyl)-4-oxo-1,5,9-triaza-cyclotridecane-1,5,9-tricarboxylic acid 1-benzyl ester 5,9-di-tert-butyl ester