Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-

Base Information

• Chemical Name: Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-
• CAS No.: 17162-83-3
• Molecular Formula: C24H21NOP2S
• Molecular Weight: 433.45
• DSSTox Substance ID: DTXSID40473330
• Nikkaji Number: J1.270.207H
• Wikidata: Q82302664
• Mol file: 17162-83-3.mol

Synonyms:DTXSID40473330;Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-;17162-83-3

Chemical Property of Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-

Chemical Property:

• XLogP3: 6.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 433.08190946
• Heavy Atom Count: 29
• Complexity: 556

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=O)(C2=CC=CC=C2)NP(=S)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl-

There total 3 articles about Phosphinic amide, N-(diphenylphosphinothioyl)-P,P-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(diphenylphosphinoamino)diphenylphosphine oxide (7648-76-2) → N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide (17162-83-3)

Guidance literature:

With sulfur; In tetrahydrofuran; for 1h;

Reference yield:

Bis(diphenylphosphanyl)amine (2960-37-4) → N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide (17162-83-3)

Guidance literature:

Multi-step reaction with 2 steps

1: peroxide

2: S₈

With sulfur; dihydrogen peroxide;

DOI:10.1039/DT9960002893

Reference yield:

→ N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide (17162-83-3)

Guidance literature:

Tetraphenyl-thio-imidodiphosphinsaeure-chlorid, W. (Methode A);

upstream raw materials:

(diphenylphosphinoamino)diphenylphosphine oxide

Bis(diphenylphosphanyl)amine

Downstream raw materials:

[Co(HN(OPPh₂)(SPPh₂)-O)2I₂]

dimethylgallium[η2-S,O-[Ph2P(S)NP(O)Ph2]]

N-(methylthio diphenylphosphoranylidene)-P,P-diphenylphosphinic amide

tetraphenylimidothioxodiphosphinic acid potassium salt