allyl N-[(mesitylsulfonyl)-oxy]carbamate

Base Information

• Chemical Name: allyl N-[(mesitylsulfonyl)-oxy]carbamate
• CAS No.: 172288-23-2
• Molecular Formula: C13H17NO5S
• Molecular Weight: 299.348
• DSSTox Substance ID: DTXSID00443857
• Nikkaji Number: J694.606B
• Wikidata: Q82261831
• Mol file: 172288-23-2.mol

Synonyms:allyl N-[(mesitylsulfonyl)-oxy]carbamate;172288-23-2;SCHEMBL6741531;DTXSID00443857;DUJORVUMHOKOEW-UHFFFAOYSA-N;Mesitylsulfonyloxycarbamic acid allyl ester

Chemical Property of allyl N-[(mesitylsulfonyl)-oxy]carbamate

Chemical Property:

• XLogP3: 2.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 6
• Exact Mass: 299.08274382
• Heavy Atom Count: 20
• Complexity: 430

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)S(=O)(=O)ONC(=O)OCC=C)C

Technology Process of allyl N-[(mesitylsulfonyl)-oxy]carbamate

There total 1 articles about allyl N-[(mesitylsulfonyl)-oxy]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-mesitylenesulphonyl chloride (773-64-8) + N-<(allyloxy)carbonyl>hydroxylamine (172288-32-3) → allyl N-<(mesitylsulfonyl)oxy>carbamate (172288-23-2)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; toluene; at 0 ℃;

DOI:10.1021/ja057389g

Reference yield: 62.0%

allyl N-<(mesitylsulfonyl)oxy>carbamate (172288-23-2) + N-methylaniline (100-61-8) → hydrazino>methylphenylamine

Guidance literature:

In toluene; at 80 ℃; for 18h;

DOI:10.1021/jo00126a062

Reference yield:

1-Bromonaphthalene (90-11-9) + allyl N-<(mesitylsulfonyl)oxy>carbamate (172288-23-2) → N-(2-naphthyl) allylcarbamate (25216-21-1)

Guidance literature:

With n-butyllithium; copper(I) bromide dimethylsulfide complex; Yield given. Multistep reaction; 1.) THF, hexane, -78 deg C, 30 min; -78 to -60 deg C, 1 h, 2.) THF, -78 deg C, 4 h;

DOI:10.1021/jo00126a062

upstream raw materials:

2-mesitylenesulphonyl chloride

N-<(allyloxy)carbonyl>hydroxylamine

Downstream raw materials:

allyl N-(p-methoxyphenyl)-carbamate

O-allyl-N-(4-methylphenyl)carbamate

N-(2-naphthyl) allylcarbamate