9-Phenyl-9-fluorenol

Base Information

• Chemical Name: 9-Phenyl-9-fluorenol
• CAS No.: 25603-67-2
• Molecular Formula: C19H14O
• Molecular Weight: 258.32
• Hs Code.: 2906299090
• Mol file: 25603-67-2.mol

Synonyms:Fluoren-9-ol,9-phenyl- (6CI,7CI,8CI);9-Hydroxy-9-phenylfluorene;9-Phenyl-9H-fluoren-9-ol;9-Phenylfluoren-9-ol;9-Phenylfluorenol;NSC 25984;

Chemical Property of 9-Phenyl-9-fluorenol

Chemical Property:

• Appearance/Colour: White Powder
• Vapor Pressure: 2.17E-08mmHg at 25°C
• Melting Point: 93-95 °C(lit.)
• Refractive Index: 1.692
• Boiling Point: 436.4 °C at 760 mmHg
• PKA: 12.52±0.20(Predicted)
• Flash Point: 166.7 °C
• PSA: 20.23000
• Density: 1.242 g/cm³
• LogP: 3.95120
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

99% ^*data from raw suppliers

9-Phenyl-9-fluorenol ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 9-Phenyl-9-fluorenol (cas# 25603-67-2) is a compound useful in organic synthesis.

Technology Process of 9-Phenyl-9-fluorenol

There total 25 articles about 9-Phenyl-9-fluorenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9-fluorenone (486-25-9,952573-42-1) + phenyllithium (591-51-5) → 9-phenyl-fluoren-9-ol (25603-67-2)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 16h; Inert atmosphere; Schlenk technique;

DOI:10.1055/s-0036-1588563

Reference yield: 99.0%

bromobenzene (108-86-1,52753-63-6) + 9-fluorenone (486-25-9,952573-42-1) → 9-phenyl-fluoren-9-ol (25603-67-2)

Guidance literature:

With bismuth(III) chloride; silver(I) bromide; magnesium; copper(ll) bromide; In tetrahydrofuran; toluene; at 96 ℃; for 12h;

DOI:10.1002/adsc.201500743

Reference yield: 96.0%

(2'-bromo-biphenyl-2-yl)-phenyl-methanone → 9-phenyl-fluoren-9-ol (25603-67-2)

Guidance literature:

With potassium acetate; tricyclohexylphosphine; hexan-1-ol; palladium diacetate; In N,N-dimethyl-formamide; at 135 ℃; for 24h;

DOI:10.1021/ja000415k

upstream raw materials:

9-fluorenone

9-Phenylfluorene

9-bromo-9-phenyl-9H-fluorene

9,9'-oxybis(9-phenyl-9H-fluorene)

Downstream raw materials:

N-(9-phenyl-9-fluorenyl)acetamide

9-phenyl-9-(2,4,6-trimethoxyphenyl)-9H-fluorene

9-bromo-9-phenyl-9H-fluorene

bis(9-phenyl-9-fluorenyl) peroxide