Silane, [4-(1,1-dimethylethyl)phenoxy]triethyl-

Base Information

• Chemical Name: Silane, [4-(1,1-dimethylethyl)phenoxy]triethyl-
• CAS No.: 17899-16-0
• Molecular Formula: C16H28OSi
• Molecular Weight: 264.483
• Mol file: 17899-16-0.mol

Synonyms:

Chemical Property of Silane, [4-(1,1-dimethylethyl)phenoxy]triethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, [4-(1,1-dimethylethyl)phenoxy]triethyl-

There total 5 articles about Silane, [4-(1,1-dimethylethyl)phenoxy]triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

triethylsilane (617-86-7) + para-tert-butylphenol (98-54-4) → {[4-(1,1-dimethylethyl)phenyl]oxy}(triethyl)silane (17899-16-0)

Guidance literature:

With tris(2,2'-bipyridyl)ruthenium dichloride; In acetonitrile; at 20 ℃; for 3h; Irradiation;

DOI:10.1039/d1cc00129a

Reference yield: 87.0%

4-tert-butyl-2-(triethylsilyl)phenol (1190881-78-7) → {[4-(1,1-dimethylethyl)phenyl]oxy}(triethyl)silane (17899-16-0)

Guidance literature:

With tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen; In dichloromethane; at 23 ℃; for 1h; under 760.051 Torr; Molecular sieve;

DOI:10.1021/ja501789x

Reference yield:

C16H27BrOSi → {[4-(1,1-dimethylethyl)phenyl]oxy}(triethyl)silane (17899-16-0)

Guidance literature:

Multi-step reaction with 2 steps

1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

2: tetrakis(actonitrile)copper(I) hexafluorophosphate; oxygen; N,N'-di-tert-butylethylenediamine / dichloromethane / 1 h / 23 °C / 760.05 Torr / Molecular sieve

With n-butyllithium; tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen; In tetrahydrofuran; hexane; dichloromethane;

DOI:10.1021/ja501789x

upstream raw materials:

para-tert-butylphenol

2-bromo-4-tert-butylphenol

4-tert-butyl-2-(triethylsilyl)phenol

triethylsilane

Downstream raw materials:

para-tert-butylphenol

Refernces

• 1、 Mehta, Meera,Goicoechea, Jose M.. "Nitrenium Salts in Lewis Acid Catalysis". . p. 2715 - 2719. Retrieved 2020/01/24.
• 2、 Esguerra, Kenneth Virgel N.,Fall, Yacoub,Petitjean, Laurène,Lumb, Jean-Philip. "Controlling the catalytic aerobic oxidation of phenols". . p. 7662 - 7668. Retrieved 2014/06/10.