Bis(tetrahydrofuran-2-yl)methane

Base Information

Chemical Name:Bis(tetrahydrofuran-2-yl)methane
CAS No.:1793-97-1
Molecular Formula:C9H16O2
Molecular Weight:156.225
Hs Code.:
DSSTox Substance ID:DTXSID10555950
Mol file:1793-97-1.mol

Synonyms:bis(tetrahydrofuran-2-yl)methane;1793-97-1;2,2'-Methylenebis(oxolane);SCHEMBL1189847;DTXSID10555950

Suppliers and Price of Bis(tetrahydrofuran-2-yl)methane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Bis(tetrahydrofuran-2-yl)methane

Chemical Property:

XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:156.115029749
Heavy Atom Count:11
Complexity:111

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC(OC1)CC2CCCO2

Technology Process of Bis(tetrahydrofuran-2-yl)methane

There total 2 articles about Bis(tetrahydrofuran-2-yl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 3937-56-2
1,9-Nonanediol

: 121498-66-6
5-(Tetrahydrofuran-2-yl)pentanol

: 1793-97-1
(tetrahydrofuryl-2 methyl)-2 tetrahydrofuranne

: 2-(3-chlorobenzoyloxypentyl)tetrahydrofuran

Guidance literature:: With [bis[(3-chlorobenzoyl)dioxy]iodo]benzene; iodine; In 1,2-dichloro-ethane; at 40 - 50 ℃; for 18h; Irradiation;
DOI:10.1002/ejoc.202100652

Reference yield:

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 107671-68-1
peroxyde de tert-butyle et de pent-4-enyle

: 121498-66-6
5-(Tetrahydrofuran-2-yl)pentanol

: 821-09-0
n-Pent-4-enyl alcohol

: 1793-97-1
(tetrahydrofuryl-2 methyl)-2 tetrahydrofuranne

: (±)-2-(pent-4-en-1-yloxy)tetrahydrofuran

: 5-(Tetrahydro-furan-2-yl)-pentanal

: C₁₃H₂₄O₃

Guidance literature:: at 140 ℃; for 10h; Mechanism; Product distribution;
DOI:10.1016/S0040-4020(01)82080-9

Reference yield:

: 1793-97-1
(tetrahydrofuryl-2 methyl)-2 tetrahydrofuranne

: 122040-35-1
(4R,6S)-6-Methoxymethoxy-1,9-bis-phenylsulfanyl-nonan-4-ol

Guidance literature:: Multi-step reaction with 6 steps

2: TMSOTf

3: 100 percent / trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 6 h / 0 °C

4: 27 percent / titanium tetrachloride / CH₂Cl₂ / 1 h / -85 °C

5: (iso-Pr)2NEt / CH₂Cl₂ / 24 h / Ambient temperature

6: tert-BuOK / 2-methyl-propan-2-ol / 0.5 h / 50 °C

With trimethylsilyl trifluoromethanesulfonate; potassium tert-butylate; titanium tetrachloride; N-ethyl-N,N-diisopropylamine; In dichloromethane; tert-butyl alcohol;
DOI:10.1016/0040-4039(88)85095-0