Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-

Base Information

Chemical Name:Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-
CAS No.:29743-02-0
Molecular Formula:C23H15 As O5 W
Molecular Weight:631.14
Hs Code.:

Synonyms:Tungsten,pentacarbonyl(triphenylarsine)- (8CI); Arsine, triphenyl-, tungsten complex;Pentacarbonyl(triphenylarsine)tungsten

Suppliers and Price of Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 6 raw suppliers

Chemical Property of Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-

Chemical Property:

PSA：0.00000
LogP:1.72980

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-

There total 2 articles about Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14040-11-0
tungsten hexacarbonyl

: 603-32-7
triphenyl-arsane

: 29743-02-0
pentacarbonyl(triphenylarsine)tungsten⁽⁰⁾

Guidance literature:: With tetrahydrofuran; In tetrahydrofuran; Irradiation (UV/VIS); N2 atmosphere; addn. of ligand to photolysed metal carbonyl in THF; solvent removal (vac.), sublimation (vac., 1 Torr, 60°C), washing (hexane), dissoln. (acetone), repptn. (water), chromy. (Kieselgel 60, hexane), recrystn. (hexane);
DOI:10.1016/0022-2860(94)08333-9

Reference yield:

: 14040-11-0
tungsten hexacarbonyl

: 603-32-7
triphenyl-arsane

: 32370-66-4
cis-tetracarbonylbis(AsPh₃)tungsten(O)

: 29743-02-0
pentacarbonyl(triphenylarsine)tungsten⁽⁰⁾

Guidance literature:: With THF; In tetrahydrofuran; Irradiation (UV/VIS); N2-atmosphere; photolysis of hexacaronyl, addn. of ligand; evapn., sublimation off of unreacted hexacarbonyl (60°C, vac.), washing (cold hexane), chromy. (SiO2, hexane), recrystn. (hexane);
DOI:10.1039/DT9940002827

Reference yield: 76.6%

: 29743-02-0
pentacarbonyl(triphenylarsine)tungsten⁽⁰⁾

: 102-08-9
N,N-diphenylthiourea

: 796047-49-9
cis-tetracarbonyl(sym-diphenylthiourea)(triphenylarsine)tungsten⁽⁰⁾

Guidance literature:: In xylene; under Ar or vac., 1 equiv. of S-compd., reflux for 5 h; soln. was cooled to room temp., solvent was removed in vac., residue waswashed 4-5 times with petroleum ether (40-60 °C), dried in vac., elem. anal.;
DOI:10.1515/znb-2004-0512