trans-Benzo(j)fluoranthene-9,10-diol

Base Information

Chemical Name:trans-Benzo(j)fluoranthene-9,10-diol
CAS No.:76479-14-6
Molecular Formula:C₂₀H₁₄O₂
Molecular Weight:286.33
Hs Code.:
Nikkaji Number:J535.506K

Synonyms:76479-14-6;CCRIS 8255;trans-Benzo(j)fluoranthene-9,10-diol;trans-9,10-Dihydrobenzo(j)fluoranthene-9,10-diol;Benzo(j)fluoranthene-9,10-diol, 9,10-dihydro-, trans-;TRANS-9,10-DIHYDRO-9,10-DIHYDROXYBENZO[J]FLUORANTHENE

Suppliers and Price of trans-Benzo(j)fluoranthene-9,10-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of trans-Benzo(j)fluoranthene-9,10-diol

Chemical Property:

Vapor Pressure:4.47E-13mmHg at 25°C
Boiling Point:553.3°Cat760mmHg
Flash Point:268.6°C
Density:1.46g/cm³
XLogP3:3.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:286.099379685
Heavy Atom Count:22
Complexity:472

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC2=C3C(=C1)C4=C(C3=CC=C2)C5=C(C=C4)C(C(C=C5)O)O
Isomeric SMILES:C1=CC2=C3C(=C1)C4=C(C3=CC=C2)C5=C(C=C4)[C@@H]([C@H](C=C5)O)O

Technology Process of trans-Benzo(j)fluoranthene-9,10-diol

There total 15 articles about trans-Benzo(j)fluoranthene-9,10-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 106542-97-6
benzofluoranthene-9,10-dione

: 76479-14-6
trans-9,10-dihydro-9,10-dihydroxybenzofluoranthene

Guidance literature:: With potassium borohydride; oxygen; In ethanol; for 2h;
DOI:10.1021/jo00381a025

Reference yield: 24.0%

: 77061-17-7
trans-9,10-bis(benzoyloxy)-9,10-dihydrobenzofluoranthene

: 76479-14-6
trans-9,10-dihydro-9,10-dihydroxybenzofluoranthene

Guidance literature:: With sodium methylate; In tetrahydrofuran; methanol; for 0.5h; Ambient temperature;
DOI:10.1021/jo00325a028

Reference yield:

: 77096-72-1
7-methyl-6b,7,10,10a-tetrahydrofluoranthene

: 76479-14-6
trans-9,10-dihydro-9,10-dihydroxybenzofluoranthene

Guidance literature:: Multi-step reaction with 14 steps

1: 80 percent / DDQ / xylene / 5 h / Heating

2: 80 percent / N-bromosuccinimide, benzoyl peroxide / CCl₄ / 3 h / Heating

3: 78 percent / diethyl ether / 30 h / Heating

4: 1.) diborane, 2.) 30percent H₂O₂ / 1.) THF, from 0 deg C to room temp., 8 h, 2.) reflux, 1 h

5: pyridinium chlorochromate / CH₂Cl₂ / 1 h / 20 °C

6: 85 percent / AgNO₃, 1.5 KOH / ethanol; H₂O / 2 h

7: SOCl₂ / benzene / 3 h / Heating

8: 1.) AlCl₃ / CS₂ / 1.) 0 deg C, 2.) reflux, 10 min

9: LiAlH₄ / tetrahydrofuran / 0.33 h / 20 °C

10: 60 percent / conc. H₂SO₄ / acetic acid / 3 h / 60 °C

11: 62 percent / 1.) I₂ / benzene / 1.) reflux, 2.) reflux, 2.5 h

12: 30 percent / N-bromsuccinimide, α,α'-azobis(isobutyronitrile) / CCl4 / 2 h / Heating

13: 60 percent / 1,5-diazabicyclo<4.3.0>non-5-ene / tetrahydrofuran / 3 h / 0 °C

14: 24 percent / sodium methoxide / tetrahydrofuran; methanol / 0.5 h / Ambient temperature

With potassium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; aluminium trichloride; thionyl chloride; Perbenzoic acid; sulfuric acid; azobisisobutyronitrile; DBN; dihydrogen peroxide; iodine; sodium methylate; silver nitrate; pyridinium chlorochromate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diborane; In tetrahydrofuran; methanol; carbon disulfide; tetrachloromethane; diethyl ether; ethanol; dichloromethane; water; acetic acid; xylene; benzene;
DOI:10.1021/jo00325a028