1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-

Base Information

Chemical Name:1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-
CAS No.:188608-71-1
Molecular Formula:C11H11NOS
Molecular Weight:205.28
Hs Code.:
DSSTox Substance ID:DTXSID50450879
Wikidata:Q82270711

Synonyms:1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-;188608-71-1;DTXSID50450879

Suppliers and Price of 1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-

Chemical Property:

XLogP3:2.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:205.05613515
Heavy Atom Count:14
Complexity:211

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)C2=CC=CN2
Isomeric SMILES:CC1=CC=C(C=C1)[S@](=O)C2=CC=CN2

Technology Process of 1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]-

There total 9 articles about 1H-Pyrrole, 2-[(S)-(4-methylphenyl)sulfinyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 5176-27-2
N-tert-butyloxycarbonyl-pyrrole

: 1517-82-4
(1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate

: 188608-71-1
(S_S)-2-(p-Tolylsulfinyl)pyrrole

Guidance literature:: N-tert-butyloxycarbonyl-pyrrole; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h;

(1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate; In tetrahydrofuran; hexane; at -78 ℃; for 17h;

Reference yield: 60.0%

: 5176-27-2
N-tert-butyloxycarbonyl-pyrrole

: (-)-menthyl (S)-p-toluenesulfinate

: 188608-71-1
(S_S)-2-(p-Tolylsulfinyl)pyrrole

Guidance literature:: N-tert-butyloxycarbonyl-pyrrole; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h;

(-)-menthyl (S)-p-toluenesulfinate; In tetrahydrofuran; hexane; at -78 ℃; for 24h; Further stages.;
DOI:10.1016/j.tet.2003.12.067

Reference yield:

: 188608-77-7
(S_S)-N-Crotonyl-2-(p-tolylsulfinyl)pyrrole

: 188608-71-1
(S_S)-2-(p-Tolylsulfinyl)pyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: AlCl₃ / CH₂Cl₂ / 25 °C

With aluminium trichloride; In dichloromethane;
DOI:10.1246/cl.1997.145