(4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone

Base Information

Chemical Name:(4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone
CAS No.:189017-49-0
Molecular Formula:C16H14O2
Molecular Weight:238.286
Hs Code.:
DSSTox Substance ID:DTXSID20508199
Nikkaji Number:J986.689B
Wikidata:Q82364933

Synonyms:DTXSID20508199;189017-49-0;(4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone

Suppliers and Price of (4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of (4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:238.099379685
Heavy Atom Count:18
Complexity:298

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C(=O)C2C(O2)C3=CC=CC=C3
Isomeric SMILES:CC1=CC=C(C=C1)C(=O)[C@@H]2[C@H](O2)C3=CC=CC=C3

Technology Process of (4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone

There total 13 articles about (4-Methylphenyl)[(2S,3R)-3-phenyloxiran-2-yl]methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 14802-30-3
(E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-one

: 189017-49-0
(αS,βR)-2,3-epoxy-4'-methyl-3-phenylpropiophenone

Guidance literature:: With C₃₃H₃₄N₃O₂⁽¹⁺⁾*Br^(1-); dihydrogen peroxide; sodium hydroxide; In diethyl ether; toluene; at 5 ℃; for 1h; enantioselective reaction;
DOI:10.1021/acs.orglett.0c03272

Reference yield: 98.0%

: 4224-96-8
3-phenyl-1-p-tolylprop-2-en-1-one

: 189017-49-0
(αS,βR)-2,3-epoxy-4'-methyl-3-phenylpropiophenone

Guidance literature:: With tert.-butylhydroperoxide; [(Me₃Si)₂N]₃Yb^III(μ-Cl)Li(THF)₃; (S)-2,4-di-tert-butyl-6-[[2-(hydroxydiphenylmethyl)pyrrolidin-1-yl]methyl]phenol; In tetrahydrofuran; at 20 ℃; for 4h; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.5b00833

Reference yield: 87.0%

: 14802-30-3
(E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-one

: 32046-97-2,32157-66-7,132490-25-6
(αR,βS)-2,3-epoxy-4'-methyl-3-phenylpropiophenone

: 189017-49-0
(αS,βR)-2,3-epoxy-4'-methyl-3-phenylpropiophenone

Guidance literature:: With sodium hydroxide; poly-L-leucine polymer; dihydrogen peroxide; In tetrachloromethane; for 42h; Title compound not separated from byproducts; Ambient temperature;
DOI:10.1016/S0040-4039(00)97101-6