Technology Process of Silane,
(1,1-dimethylethyl)[[10-(1,3-dioxolan-2-yl)-3,7,11-trimethyl-9-(phenylsulf
onyl)-2,6-dodecadienyl]oxy]dimethyl-, (E,E)-
There total 8 articles about Silane,
(1,1-dimethylethyl)[[10-(1,3-dioxolan-2-yl)-3,7,11-trimethyl-9-(phenylsulf
onyl)-2,6-dodecadienyl]oxy]dimethyl-, (E,E)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium;
In
tetrahydrofuran;
1.) -78 to -30 deg C, 2 h, 2.) -30 to r.t., 2 h;
DOI:10.1039/a606551a
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 40 percent / SeO2, salicylic acid, 70percent t-BuOOH / CH2Cl2 / 30 h
2: 75 percent / I2, PPh3, imidazole / diethyl ether; acetonitrile / 1 h
3: 82 percent / BuLi / tetrahydrofuran / 1.) -78 to -30 deg C, 2 h, 2.) -30 to r.t., 2 h
With
1H-imidazole; tert.-butylhydroperoxide; n-butyllithium; selenium(IV) oxide; iodine; triphenylphosphine; salicylic acid;
In
tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1039/a606551a
- Guidance literature:
-
Multi-step reaction with 6 steps
1: p-TsOH / acetone / 5 h
2: 82 percent / PPh3, NBS, pyridine / CH2Cl2 / 15 h / Ambient temperature
3: 75 percent / dimethylformamide / 15 h / 70 °C
4: 95 percent / aq. HIO4 / tetrahydrofuran / 5 h
5: 95 percent / p-TsOH / benzene / 6 h / Heating
6: 82 percent / BuLi / tetrahydrofuran / 1.) -78 to -30 deg C, 2 h, 2.) -30 to r.t., 2 h
With
pyridine; N-Bromosuccinimide; n-butyllithium; toluene-4-sulfonic acid; periodic acid; triphenylphosphine;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1039/a606551a
