2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)-

Base Information

Chemical Name:2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)-
CAS No.:189437-75-0
Molecular Formula:C28H38O3Si
Molecular Weight:450.693
Hs Code.:

Synonyms:

Suppliers and Price of 2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)-

There total 1 articles about 2,6-Octadienoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-2-ethyl-6-methyl-, methyl ester, (E,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24448-83-7
2-(triphenyl-λ⁵-phosphanylidene)-butyric acid methyl ester

: 139109-02-7
(E)-6-((tert-butyldiphenylsilyl)oxy)-4-methylhex-4-enal

: methyl (2Z,6E)-8-[(tert-butyldiphenylsilyl)oxy]-2-ethyl-6-methyl-2,6-octadien-1-oate

: 189437-75-0
methyl (2E,6E)-8-[(tert-butyldiphenylsilyl)oxy]-2-ethyl-6-methyl-2,6-octadien-1-oate

Guidance literature:: In tetrahydrofuran; for 168h; Yield given. Yields of byproduct given; Ambient temperature;
DOI:10.1021/jo962008q

Reference yield: 94.0%

: 189437-75-0
methyl (2E,6E)-8-[(tert-butyldiphenylsilyl)oxy]-2-ethyl-6-methyl-2,6-octadien-1-oate

: 189437-77-2
(2E,6E)-8-[(tert-butyldiphenylsilyl)oxy]-2-ethyl-6-methyl-2,6-octadien-1-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -40 - 0 ℃; for 2h;
DOI:10.1021/jo962008q

Reference yield:

: 189437-75-0
methyl (2E,6E)-8-[(tert-butyldiphenylsilyl)oxy]-2-ethyl-6-methyl-2,6-octadien-1-oate

: tert-Butyl-diphenyl-((2E,6E,10Z)-3,7,11-trimethyl-trideca-2,6,10-trienyloxy)-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / DIBALH / tetrahydrofuran; hexane / 2 h / -40 - 0 °C

2: 1.) MsCl, Et₃N, 2.) LiCl / 1.) CH₂Cl₂, -40 deg C, 1 h, 2.) THF, 0 deg C, 2 h

3: 72 percent / LiEt₃BH / tetrahydrofuran / 2 h / 0 °C

4: 82 percent / TBAF / tetrahydrofuran / 1.) 0 deg C, 1 h, 2.) room temperature, 3 h

5: 1.) MsCl, Et₃N, 2.) LiCl / 1.) CH₂Cl₂, -40 deg C, 1 h, 2.) THF, 0 deg C, 2 h

6: 1.) BaI₂*H₂O, biphenyl radical / 1.) THF, -78 deg C, 15 min, 2.) THF, -78 deg C, 1 h

With biphenyl; barium(II) iodide; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; lithium triethylborohydride; methanesulfonyl chloride; triethylamine; lithium chloride; In tetrahydrofuran; hexane;
DOI:10.1021/jo962008q