(1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol

Base Information

Chemical Name:(1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol
CAS No.:80446-23-7
Molecular Formula:C18H14O3
Molecular Weight:278.302
Hs Code.:
Mol file:80446-23-7.mol

Synonyms:(+)-(1R,2S,3S,4R)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenz[a]anthracene;

Suppliers and Price of (1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 3 raw suppliers

Chemical Property of (1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol

Chemical Property:

Vapor Pressure:1.03E-13mmHg at 25°C
Boiling Point:567.5°Cat760mmHg
Flash Point:297°C
PSA：52.99000
Density:1.478g/cm³
LogP:2.84080

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol

There total 10 articles about (1aS)-1aα,2,3,11cα-Tetrahydrobenzo[6,7]phenanthro[3,4-b]oxirene-2β,3α-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.5%

: 67335-42-6
(-)-trans-(3R,4R)-3,4-dihydroxy-3,4-dihydrobenz anthracene

: 80446-23-7
(+)-(1R,2S,3S,4R)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenz anthracene

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; for 0.25h; Ambient temperature;
DOI:10.1021/jo00345a043

Reference yield:

: 63438-26-6,63493-01-6,64551-89-9,64598-80-7,64598-81-8,80433-78-9,80433-79-0,80433-81-4,80446-23-7
C₁₈H₁₄O₃

Guidance literature:: entspr. Dihydrodiol, 1) N-Bromacetamid, 2) Amberlit (OH-Form); Geschwindigkeitskonstante;

Reference yield:

: 60967-89-7,64501-86-6,60839-18-1,67335-42-6,67335-43-7
(+/-)-trans-3,4-dihydroxy-3,4-dihydrobenz anthracene

: 80446-23-7
(+)-(1R,2S,3S,4R)-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenz anthracene

Guidance literature:: Multi-step reaction with 3 steps

1: 19 percent / pyridine / 0 - 5 °C

2: 95 percent / NaOCH₃ / methanol; tetrahydrofuran / 1 h / Ambient temperature

3: 78.5 percent / m-chloroperoxybenzoic acid / tetrahydrofuran / 0.25 h / Ambient temperature

With pyridine; sodium methylate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol;
DOI:10.1021/jo00345a043