2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)-

Base Information

Chemical Name:2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)-
CAS No.:189886-25-7
Molecular Formula:C12H13BrO2
Molecular Weight:269.13400
Hs Code.:
Mol file:189886-25-7.mol

Synonyms:(E)-iso-propyl 3-(4-bromophenyl)propanoate;3-(4-bromophenyl)acrylic acid isopropyl ester;

Suppliers and Price of 2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of 2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)-

Chemical Property:

PSA：26.30000
LogP:3.41390

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)-

There total 2 articles about 2-Propenoic acid, 3-(4-bromophenyl)-, 1-methylethyl ester, (2E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1200-07-3,5676-63-1,17916-60-8
trans-4-bromocinnamic acid

: 67-63-0,8013-70-5
isopropyl alcohol

: 189886-25-7
(E)-iso-propyl 3-(4-bromophenyl)prop-2-enoate

Guidance literature:: With sulfuric acid; for 24h; Heating;
DOI:10.1039/a606968a

Reference yield:

: C₁₂H₁₃BrN₂O₂

: C₁₂H₁₃BrO₂

: 189886-25-7
(E)-iso-propyl 3-(4-bromophenyl)prop-2-enoate

Guidance literature:: With trityl tetrafluoroborate; In dichloromethane; at 20 ℃; for 0.166667h; Overall yield = 75 percent; Overall yield = 80.8 mg; diastereoselective reaction;
DOI:10.1021/acs.orglett.9b03005

Reference yield: 90.0%

: 189886-25-7
(E)-iso-propyl 3-(4-bromophenyl)prop-2-enoate

: 3-(4-aminophenyl)acrylic acid isopropyl ester

Guidance literature:: (E)-iso-propyl 3-(4-bromophenyl)prop-2-enoate; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; In toluene; for 0.25h; Inert atmosphere;

With lithium hexamethyldisilazane; In toluene; at 20 ℃; Inert atmosphere;

With hydrogenchloride; In water; toluene; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1039/c2ob06801j