1,1-DIETHYLCYCLOPROPANE

Base Information

• Chemical Name: 1,1-DIETHYLCYCLOPROPANE
• CAS No.: 1003-19-6
• Molecular Formula: C7H14
• Molecular Weight: 98.1882
• Hs Code.: 2902199090
• European Community (EC) Number: 213-703-4
• DSSTox Substance ID: DTXSID8061391
• Nikkaji Number: J217.109K
• Wikidata: Q81989447
• Mol file: 1003-19-6.mol

Synonyms:1,1-Diethylcyclopropane;gem-Diethylcyclopropane

Chemical Property of 1,1-DIETHYLCYCLOPROPANE

Chemical Property:

• Vapor Pressure: 70.4mmHg at 25°C
• Melting Point: -105.9°C
• Refractive Index: 1.3915 (estimate)
• Boiling Point: 87.9°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.774g/cm³
• LogP: 2.58660
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 98.109550447
• Heavy Atom Count: 7
• Complexity: 54.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1(CC1)CC

Technology Process of 1,1-DIETHYLCYCLOPROPANE

There total 5 articles about 1,1-DIETHYLCYCLOPROPANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-dibromo-2,2-diethylpropane (67969-84-0) → 1,1-diethylcyclopropane (1003-19-6)

Guidance literature:

With ethanol; zinc;

Reference yield:

1,1-Dibromo-2,2-diethylcyclopropan (201987-86-2) → 1,1-diethylcyclopropane (1003-19-6)

Guidance literature:

With methanol; sodium;

DOI:10.1039/jr9650000191

Reference yield:

2-ethyl-1-butene (760-21-4) + methylene iodate → 1,1-diethylcyclopropane (1003-19-6)

Guidance literature:

With copper; zinc;

DOI:10.1002/mrc.1270160120

upstream raw materials:

1,3-dibromo-2,2-diethylpropane

1,1-Dibromo-2,2-diethylcyclopropan

2-ethyl-1-butene

1,3-diiodo-2,2-diethylpropane

Downstream raw materials:

3,3-dimethylpentane

3-ethyl-2-pentene

3-ethyl-3-methoxypentane

Refernces

• 1、 Bailey, William F.,Gagnier, R. Paul. "REACTION OF α,ο-DIIODIDES WITH t-BUTYLLITHIUM: FACILE ROUTE TO THREE-, FOUR- AND FIVE-MEMBERED CYCLOALKANES". . p. 5123 - 5126. Retrieved 1982.