trans-1,4-Dimethylcyclohexane

Base Information

• Chemical Name: trans-1,4-Dimethylcyclohexane
• CAS No.: 2207-04-7
• Molecular Formula: C8H16
• Molecular Weight: 112.215
• Hs Code.: 2902199090
• Mol file: 2207-04-7.mol

Synonyms:trans-1,4-Dimethylcyclohexane

Chemical Property of trans-1,4-Dimethylcyclohexane

Chemical Property:

• Vapor Pressure: 19.14mmHg at 25°C
• Melting Point: -36.9 °C
• Boiling Point: 125.9°Cat760mmHg
• Flash Point: 15.6°C
• PSA: 0.00000
• Density: 0.766g/cm³
• LogP: 2.83260

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): F,Xn
• Hazard Codes: F,Xn

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of trans-1,4-Dimethylcyclohexane

There total 42 articles about trans-1,4-Dimethylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

para-xylene (106-42-3) → trans-1,4-dimethylcyclohexane (2207-04-7) + cis-1,4-dimethylcyclohexane (624-29-3)

Guidance literature:

With hydrogen; tetra(n-butyl)ammonium hydrogensulfate; rhodium colloidal catalyst; In water; at 36 ℃; for 62h; under 180014 Torr; pH=7.5;

Reference yield: 43.0%

Cyclooctan (292-64-8) → ethyl-cyclohexane (1678-91-7) + cis-1,3-dimethylcyclohexane (638-04-0) + trans-1,4-dimethylcyclohexane (2207-04-7) + 1,2-trans-dimethylcyclohexane (6876-23-9)

Guidance literature:

With triisobutylaluminum; palladium dichloride; In tetrachloromethane; at 8 - 50 ℃; for 2h; Further byproducts given;

DOI:10.1023/A:1014047915995

Reference yield: 24.0%

3-Methylentricyclo<4.1.0.02,7>heptan (74498-75-2) → methylcycloheptane (4126-78-7) + trans-1,4-dimethylcyclohexane (2207-04-7) + cis-1,4-dimethylcyclohexane (624-29-3)

Guidance literature:

With hydrogen; palladium on activated charcoal;

upstream raw materials:

cis-1,4-dimethylcyclohexane

para-xylene

trans-1,4-bis-(acetylsulfanyl-methyl)-cyclohexane

1,4-dimethylcyclohexyl chloride

Downstream raw materials:

1,4c-dimethyl-cyclohex-r-yl hydroperoxide

1,4-dimethyl-cyclohexane-1r,4t-diyl dihydroperoxide

N(cis-1.4-Dimethylcyclohexyl)methansulfonamid

n-pentyl methyl ketone

Refernces

• 1、 Miyamura, Hiroyuki,Suzuki, Aya,Yasukawa, Tomohiro,Kobayashi, Shu. "Polysilane-Immobilized Rh-Pt Bimetallic Nanoparticles as Powerful Arene Hydrogenation Catalysts: Synthesis, Reactions under Batch and Flow Conditions and Reaction Mechanism". supporting information. p. 11325 - 11334. Retrieved 2018/09/06.
• 2、 Karakhanov,Maximov,Zolotukhina,Terenina,Vutolkina. "Nanoheterogeneous ruthenium-containing catalysts based on dendrimers in the hydrogenation of aromatic compounds under two-phase conditions". . p. 491 - 502. Retrieved 2016/07/29.