Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-

Base Information

Chemical Name:Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-
CAS No.:194015-14-0
Molecular Formula:C21H33BrO2Si
Molecular Weight:425.481
Hs Code.:
DSSTox Substance ID:DTXSID80441614
Wikidata:Q82258452
Mol file:194015-14-0.mol

Synonyms:DTXSID80441614;Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-;194015-14-0

Suppliers and Price of Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:10
Exact Mass:424.14332
Heavy Atom Count:25
Complexity:444

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)CCOC1=CC(=C(C=C1C#C[Si](C)(C)C)OCCC(C)C)Br

Technology Process of Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl-

There total 1 articles about Silane, [[4-bromo-2,5-bis(3-methylbutoxy)phenyl]ethynyl]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 194015-12-8
1-Bromo-4-iodo-2,5-bis-(3-methyl-butoxy)-benzene

: 1066-54-2
trimethylsilylacetylene

: 194015-14-0
[4-Bromo-2,5-bis-(3-methyl-butoxy)-phenylethynyl]-trimethyl-silane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine; Ambient temperature;
DOI:10.1021/jo970548x

Reference yield: 98.0%

: 194015-14-0
[4-Bromo-2,5-bis-(3-methyl-butoxy)-phenylethynyl]-trimethyl-silane

: 194015-33-3
1-Bromo-4-ethynyl-2,5-bis-(3-methyl-butoxy)-benzene

Guidance literature:: With sodium hydroxide; In methanol; for 2h; Ambient temperature;
DOI:10.1021/jo970548x

Reference yield:

: 194015-14-0
[4-Bromo-2,5-bis-(3-methyl-butoxy)-phenylethynyl]-trimethyl-silane

: 194015-37-7
C₇₂H₉₇BrO₈

Guidance literature:: Multi-step reaction with 5 steps

1: 98 percent / aq. NaOH / methanol / 2 h / Ambient temperature

2: 57 percent / Et₂NH, Pd(PPh₃)2Cl₂, CuI / Ambient temperature

3: 100 percent / aq. NaOH / methanol; tetrahydrofuran / 2 h / Ambient temperature

4: 53 percent / Et₂NH, Pd(PPh₃)2Cl₂, CuI / Ambient temperature

5: 99 percent / aq. NaOH / methanol; tetrahydrofuran / 2 h / Ambient temperature

With bis-triphenylphosphine-palladium(II) chloride; sodium hydroxide; copper(l) iodide; diethylamine; In tetrahydrofuran; methanol;
DOI:10.1021/jo970548x