Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside

Base Information

Chemical Name:Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside
CAS No.:85439-70-9
Molecular Formula:C₇H₁₂O₃
Molecular Weight:144.17
Hs Code.:
NSC Number:112858
DSSTox Substance ID:DTXSID001005964

Synonyms:85439-70-9;methyl 3,4-anhydro-2,6-dideoxyhexopyranoside;NSC112858;DTXSID001005964;NSC-112858

Suppliers and Price of Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside

Chemical Property:

Vapor Pressure:0.737mmHg at 25°C
Boiling Point:190.8°Cat760mmHg
Flash Point:60.6°C
Density:1.12g/cm³
XLogP3:0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:144.078644241
Heavy Atom Count:10
Complexity:137

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C2C(O2)CC(O1)OC

Technology Process of Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside

There total 18 articles about Methyl 3,4-anhydro-2,6-dideoxyhexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 71122-35-5
methyl-3-O-benzoyl-2,6-didesoxy-4-O-methylsulfonyl-α-L-arabino-hexopyranoside

: 85439-70-9
methyl-3,4-anhydro-2,6-didesoxy-α-L-lyxo-hexopyranoside

Guidance literature:: With sodium methylate; In methanol; Ambient temperature;
DOI:10.1016/0008-6215(83)88235-4

Reference yield:

: 87858-14-8
3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hex-1-enitol

: 85439-70-9
methyl-3,4-anhydro-2,6-didesoxy-α-L-lyxo-hexopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 78 percent / H₂ / 10percent Pd/C / ethyl acetate / Ambient temperature

2: 1) Ba(OH)2*8H₂O, 2) H₂SO₄ / 1) water, room temp., 2) <10 degC -> room temp., overnight

3: AG 50-X₄(H⁺) / 120 h / Ambient temperature

5: 14 percent / pyridine / refrigerator, overnight

6: AG 1-X₄(OH^-) / methanol / 2 h / Ambient temperature

With pyridine; barium dihydroxide; AG 1-X₄(OH^-); AG 50-X₄(H⁺); sulfuric acid; hydrogen; palladium on activated charcoal; In methanol; ethyl acetate;
DOI:10.1021/jo00174a028

Reference yield:

: 87858-15-9
3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hexitol

: 85439-70-9
methyl-3,4-anhydro-2,6-didesoxy-α-L-lyxo-hexopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 1) Ba(OH)2*8H₂O, 2) H₂SO₄ / 1) water, room temp., 2) <10 degC -> room temp., overnight

2: AG 50-X₄(H⁺) / 120 h / Ambient temperature

4: 14 percent / pyridine / refrigerator, overnight

5: AG 1-X₄(OH^-) / methanol / 2 h / Ambient temperature

With pyridine; barium dihydroxide; AG 1-X₄(OH^-); AG 50-X₄(H⁺); sulfuric acid; In methanol;
DOI:10.1021/jo00174a028