Benzenamine, N-2-butenyl-N-methyl-

Base Information

• Chemical Name: Benzenamine, N-2-butenyl-N-methyl-
• CAS No.: 30211-55-3
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• NSC Number: 128146
• Nikkaji Number: J1.505.883H
• Mol file: 30211-55-3.mol

Synonyms:Benzenamine, N-2-butenyl-N-methyl-;NSC128146;30211-55-3;XNLGOZLAANBDMA-ONEGZZNKSA-N;(E)-But-2-enyl-methyl-phenyl-amine;N-[(E)-2-Butenyl]-N-methylaniline;AKOS024263121;NSC-128146;N-[(2E)-2-Butenyl]-N-methylaniline #

Chemical Property of Benzenamine, N-2-butenyl-N-methyl-

Chemical Property:

• Vapor Pressure: 0.0498mmHg at 25°C
• Boiling Point: 235.5°Cat760mmHg
• Flash Point: 94.8°C
• Density: 0.945g/cm³
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 161.120449483
• Heavy Atom Count: 12
• Complexity: 134

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCN(C)C1=CC=CC=C1
• Isomeric SMILES: C/C=C/CN(C)C1=CC=CC=C1

Technology Process of Benzenamine, N-2-butenyl-N-methyl-

There total 7 articles about Benzenamine, N-2-butenyl-N-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(E/Z)-2-buten-1-ol (6117-91-5,542-72-3) + N-methylaniline (100-61-8) → 4-(N-methyl-N-phenylamino)-2-butene (30211-55-3)

Guidance literature:

With triethyl borane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; at 20 ℃; for 30h;

DOI:10.1039/b210920d

Reference yield: 88.0%

2-hydroxy-3-butene (598-32-3) + N-methylaniline (100-61-8) → 4-(N-methyl-N-phenylamino)-2-butene (30211-55-3)

Guidance literature:

With triethyl borane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; at 20 ℃; for 30h;

DOI:10.1039/b210920d

Reference yield: 65.0%

((E)-But-2-enyl)-methyl-(2-oxo-2-phenyl-ethyl)-phenyl-ammonium; bromide → 4-(N-methyl-N-phenylamino)-2-butene (30211-55-3) + N-methyl-N-phenacylaniline (32119-53-2) + 3-methyl-2-(methyl-phenyl-amino)-1-phenyl-pent-4-en-1-one

Guidance literature:

With sodium carbonate; at 20 - 60 ℃;

DOI:10.1023/B:RUGC.0000016031.82173.59

upstream raw materials:

(E/Z)-crotyl bromide

N-methylaniline

1-chloro-2-butene

2-hydroxy-3-butene

Downstream raw materials:

methyl(phenyl)cyanamide

(N-methyl N-phenylamino)-4 butanol-2