[2.2]Orthocyclophane

Base Information

Chemical Name:[2.2]Orthocyclophane
CAS No.:1460-59-9
Molecular Formula:C16H16
Molecular Weight:208.303
Hs Code.:
Mol file:1460-59-9.mol

Synonyms:1,2:5,6-Dibenzocyclooctane;5,6,11,12-Tetrahydrodibenzo[a,e]cyclooctene; Cyclodi-o-xylylene;Dibenzocycloocta-1,5-diene; NSC 206242; [2.2]Orthocyclophane;s-Dibenzocyclooctadiene

Suppliers and Price of [2.2]Orthocyclophane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Arctom
5,6,11,12-Tetrahydrodibenzo[a,e][8]annulene
1g
$ 895.00

AK Scientific
Dibenzocycloocta-1,5-diene
1g
$ 1268.00

Total 12 raw suppliers

Chemical Property of [2.2]Orthocyclophane

Chemical Property:

Vapor Pressure:0.00121mmHg at 25°C
Boiling Point:308.8°Cat760mmHg
Flash Point:144.8°C
PSA：0.00000
Density:1.033g/cm³
LogP:3.57040

Purity/Quality:

97% ^*data from raw suppliers

5,6,11,12-Tetrahydrodibenzo[a,e][8]annulene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [2.2]Orthocyclophane

There total 57 articles about [2.2]Orthocyclophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: 91-13-4
α,α'-dibromo-o-xylene

: 36673-36-6,111408-20-9,14126-37-5,54053-52-0
dibromobis(triphenylphosphine)nickel(II)

: 1460-59-9
5,6,11,12-tetrahydro-dibenzo[a,e]cyclooctene

Guidance literature:: In diethyl ether; under Ar, into stirred soln. of C6H4(CH2Br)2 in ether Ni complex introduced at -20°C over 1 h;
DOI:10.1016/S0022-328X(00)83863-2

Reference yield: 91.0%

: 1032936-97-2,223682-16-4,223682-17-5,262-89-5
dibenzo[a,e]cyclooctatetraene

: 1460-59-9
5,6,11,12-tetrahydro-dibenzo[a,e]cyclooctene

Guidance literature:: With [Fe₃(1,1,1,3,3,3-hexamethyldisilazan-2-ide)₄]Fe(η⁶-toluene); hydrogen; at 20 ℃; for 3h; under 1425.14 Torr; chemoselective reaction; Inert atmosphere; Glovebox;
DOI:10.1002/anie.201612548