Cyclohexanamine, N-cyclohexyl-N-hydroxy-

Base Information

• Chemical Name: Cyclohexanamine, N-cyclohexyl-N-hydroxy-
• CAS No.: 19627-68-0
• Molecular Formula: C12H23NO
• Molecular Weight: 197.321
• Mol file: 19627-68-0.mol

Synonyms:

Chemical Property of Cyclohexanamine, N-cyclohexyl-N-hydroxy-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanamine, N-cyclohexyl-N-hydroxy-

There total 3 articles about Cyclohexanamine, N-cyclohexyl-N-hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

C24H32NO2P (102269-10-3) → N,N-dicyclohexylhydroxylamine (19627-68-0)

Guidance literature:

With sulfuric acid; In methanol; for 2h; Heating;

DOI:10.1055/s-1985-31359

Reference yield: 82.6%

N-cyclohexyl-cyclohexanamine (101-83-7) → N,N-dicyclohexylhydroxylamine (19627-68-0)

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at 0 ℃; for 0.166667h;

Reference yield:

1-nitrocyclohexane (1122-60-7) → cyclohexane (110-82-7,25012-93-5) + N,N-dicyclohexylhydroxylamine (19627-68-0) + N,O-Dibutyl-N-cyclohexylhydroxylamin + O-Butyl-N,N-dicyclohexylhydroxylamin (107962-73-2)

Guidance literature:

With bis(tri-n-butyltin); In benzene; at 25 ℃; for 1h; Product distribution; Irradiation; other times;

upstream raw materials:

C₂₄H₃₂NO₂P

N-cyclohexyl-cyclohexanamine

1-nitrocyclohexane

Refernces

• 1、 Murray, Robert W.,Singh, Megh. "A HIGH YIELD ONE STEP SYNTHESIS OF HYDROXYLAMINES". . p. 3509 - 3522. Retrieved 2007/10/02.
• 2、 Yaouanc, Jean Jacques,Masse, Guy,Sturtz, Georges. "Nucleophilic Oxidation with Bis Peroxide: Direct Preparation of O-Phosphinylated Aminating Reagents". . p. 807 - 810. Retrieved 2007/10/02.