2,6,10-Dodecatrienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,6Z)-

Base Information

Chemical Name:2,6,10-Dodecatrienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,6Z)-
CAS No.:20085-72-7
Molecular Formula:C₁₇H₂₈O₂
Molecular Weight:264.408
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,6,10-Dodecatrienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,6Z)-

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 2,6,10-Dodecatrienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,6Z)-

There total 8 articles about 2,6,10-Dodecatrienoic acid, 3,7,11-trimethyl-, ethyl ester, (2E,6Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 3879-26-3
(Z)-nerylacetone

: 20085-73-8
ethyl (2Z,6Z)-3,7,11-trimethyl-2,6,10-dodecatrienoate

: 20085-72-7
ethyl (2E,6Z)-3,7,11-trimethyl-2,6,10-dodecatrienoate

Guidance literature:: diethoxyphosphoryl-acetic acid ethyl ester; With sodium hydride; In tetrahydrofuran; mineral oil; at -20 ℃; for 0.5h; Inert atmosphere;

(Z)-nerylacetone; In tetrahydrofuran; mineral oil; at -20 - 25 ℃; for 16h; Inert atmosphere;
DOI:10.1021/ja106813s

Reference yield:

: 867-13-0
diethoxyphosphoryl-acetic acid ethyl ester

: 3879-26-3
(Z)-nerylacetone

: 19954-66-6,20085-71-6,20085-72-7,20085-73-8,20723-88-0,33776-65-7
ethyl 3,7,11-trimethyl-2ξ,6Z,10-dodecatrienoate

Guidance literature:: With sodium hydride; Yield given. Multistep reaction; 1.) DME, 30 min, 2.) DME, a) 25 deg C, 3 h, b) reflux, 30 min;
DOI:10.1021/jo00384a035

Reference yield:

: (Z)-2-Acetyl-5,9-dimethyl-deca-4,8-dienoic acid

: 19954-66-6,20085-71-6,20085-72-7,20085-73-8,20723-88-0,33776-65-7
ethyl 3,7,11-trimethyl-2ξ,6Z,10-dodecatrienoate

Guidance literature:: Multi-step reaction with 2 steps

1: aq. HCl

2: NaH; 15-crown-6 / tetrahydrofuran / -30 °C

With hydrogenchloride; 15-crown-6; sodium hydride; In tetrahydrofuran; 2: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/ol0513239