Silane, trimethyl(2-phenyl-2,3-butadienyl)-

Base Information

Chemical Name:Silane, trimethyl(2-phenyl-2,3-butadienyl)-
CAS No.:201345-79-1
Molecular Formula:C13H18Si
Molecular Weight:202.371
Hs Code.:
DSSTox Substance ID:DTXSID20450447
Nikkaji Number:J913.406I

Synonyms:Silane, trimethyl(2-phenyl-2,3-butadienyl)-;201345-79-1;DTXSID20450447;3-Phenyl-4-(trimethylsilyl)-1,2-butadiene

Suppliers and Price of Silane, trimethyl(2-phenyl-2,3-butadienyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, trimethyl(2-phenyl-2,3-butadienyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:202.117777109
Heavy Atom Count:14
Complexity:222

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)CC(=C=C)C1=CC=CC=C1

Technology Process of Silane, trimethyl(2-phenyl-2,3-butadienyl)-

There total 5 articles about Silane, trimethyl(2-phenyl-2,3-butadienyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 82490-61-7
3-phenyl-2-propyn-1-yl methanesulfonate

: 201345-79-1
trimethyl-(2-phenylbuta-2,3-dien-1-yl)silane

Guidance literature:: With lithium chloride; In tetrahydrofuran; diethyl ether; at -78 ℃; for 2h;
DOI:10.1021/ol047319z

Reference yield:

: 591-50-4
iodobenzene

: 201345-79-1
trimethyl-(2-phenylbuta-2,3-dien-1-yl)silane

Guidance literature:: Multi-step reaction with 3 steps

1: CuI; Et₂NH / Pd(PPh₃)2Cl₂ / 21.5 h / 20 °C

2: 71 percent / Et₃N / CH₂Cl₂ / 3.5 h / 20 °C

3: 54 percent / CuCN; LiCl / tetrahydrofuran; diethyl ether / 2 h / -78 °C

With copper(l) iodide; diethylamine; triethylamine; lithium chloride; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol047319z

Reference yield:

: 1504-58-1
3-Phenyl-2-propyn-1-ol

: 201345-79-1
trimethyl-(2-phenylbuta-2,3-dien-1-yl)silane

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / Et₃N / CH₂Cl₂ / 3.5 h / 20 °C

2: 54 percent / CuCN; LiCl / tetrahydrofuran; diethyl ether / 2 h / -78 °C

With triethylamine; lithium chloride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol047319z