[(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)

Base Information

Chemical Name:[(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)
CAS No.:62012-79-7
Molecular Formula:C16H26N2O15P2
Molecular Weight:548.3296
Hs Code.:

[(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)

Synonyms:

Suppliers and Price of [(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)

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Chemical Property of [(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:1.78g/cm³

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Technology Process of [(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name)

There total 35 articles about [(2R,3S,5R)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-2-yl]methyl (2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl dihydrogen diphosphate (non-preferred name) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 2196-62-5
thymidine 5'-(α-D-glucopyranosyl diphosphate)

: 62012-79-7
TDP-6-deoxy-D-gulose

Guidance literature:: With Salmonella enterica RfbB enzyme; Salmonella enterica RfbC enzyme; Salmonella enterica RfbD enzyme; alcohol dehydrogenase; In isopropyl alcohol; at 37 ℃; for 2.5h; pH=7.5;
DOI:10.1002/anie.200503195

Reference yield: 63.0%

: 365-08-2,92627-33-3,106119-81-7
dTTP

: 59-56-3,27251-84-9,63779-58-8,262856-84-8
α-D-glucopyranosyl-1-phosphate

: 2147-59-3,62012-79-7
thymidine 5'-diphospho-β-L-rhamnose

Guidance literature:: dTTP; α-D-glucopyranosyl-1-phosphate; With Streptococcus pneumonia serotype 23F Glc-1-P thymidylyltransferase Cps₂₃FL; nicotinamide adenine dinucleotide; β-nicotinamide adenine dinucleotide, disodium salt, reduced form; magnesium chloride; In aq. buffer; at 37 ℃; for 0.25h; pH=7.5; Enzymatic reaction;

With Streptococcus pneumonia serotype 23F dTDP-4-keto-6-deoxy-Glc-3,5-epimerase Cps₂₃FM; Streptococcus pneumonia serotype 23F dTDP-4-keto-Rham reductase Cps₂₃FO; Streptococcus pneumonia serotype 23F dTDP-Glc-4,6-dehydratase Cps₂₃FN; In aq. buffer; for 1h; pH=7.5; Enzymatic reaction;
DOI:10.1039/c6cc08366h