Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]-

Base Information

• Chemical Name: Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]-
• CAS No.: 219325-26-5
• Molecular Formula: C19H24N2
• Molecular Weight: 280.413
• DSSTox Substance ID: DTXSID60455638
• Nikkaji Number: J1.159.359C
• Mol file: 219325-26-5.mol

Synonyms:219325-26-5;Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]-;2-[1-(2,6-diisopropylphenylimino)ethyl]pyridine;SCHEMBL242518;SCHEMBL8166694;DTXSID60455638;(2,6-Diisopropylphenyl)(1-(2-pyridyl)ethylidene)amine

Chemical Property of Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]-

Chemical Property:

• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 280.193948774
• Heavy Atom Count: 21
• Complexity: 330

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=C(C(=CC=C1)C(C)C)N=C(C)C2=CC=CC=N2

Technology Process of Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]-

There total 4 articles about Benzenamine, 2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-acetylpyridine (1122-62-9) + 2,6-diisopropylbenzenamine (24544-04-5) → (2,6-diisopropylphenyl)[1-(pyridin-2-yl)ethylidene]amine (219325-26-5)

Guidance literature:

With sodium sulfate; In dichloromethane; for 72h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1002/chem.201304459

Reference yield:

(pyEA-AriPr2)2Cr → 1-indoline (496-15-1) + C38H46CrN4 + (2,6-diisopropylphenyl)[1-(pyridin-2-yl)ethylidene]amine (219325-26-5)

Guidance literature:

In benzene; at 140 ℃; for 36h; Sealed tube;

DOI:10.1021/acs.organomet.5b00385

Reference yield:

(pyEA-AriPr2)2Mn → 1-indoline (496-15-1) + C38H46MnN4 + (2,6-diisopropylphenyl)[1-(pyridin-2-yl)ethylidene]amine (219325-26-5)

Guidance literature:

In benzene; at 140 ℃; for 36h; Sealed tube;

DOI:10.1021/acs.organomet.5b00385

upstream raw materials:

2-acetylpyridine

2,6-diisopropylbenzenamine

Downstream raw materials:

[(C₅H₄N-2-CMe=NC₆H₃-2,6-(i-Pr)2)PdMeCl]

C₅H₄NC(CH₃)NC₆H₃(C₃H₇)2NiBr₂

di-μ-bromodibromobis(2,6-bis(1-methylethyl)-N-[1-(2-pyridinyl)ethylidene]phenylamine)dinickel(II)

[pyridine-2-C(CH₃)=N(2,6-(i-C₃H₇)2C₆H₃))]palladium(II) bis-trifluoroacetate