Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate

Base Information

Chemical Name:Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate
CAS No.:21987-32-6
Molecular Formula:C8H12O3
Molecular Weight:156.181
Hs Code.:
NSC Number:196152
DSSTox Substance ID:DTXSID30307877,DTXSID401244603
Nikkaji Number:J2.470.069K

Synonyms:methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate;21987-32-6;17791-35-4;methyl 7-oxa-2-norbornanecarboxylate;methyl endo-7-oxabicyclo[2.2.1]heptane-2-carboxylate;NSC196152;methyl exo-7-oxabicyclo[2.2.1]heptane-2-carboxylate;SCHEMBL5400994;DTXSID30307877;DTXSID401244603;AKOS033160635;NSC-196152;EN300-156773;methyl7-oxabicyclo[2.2.1]heptane-2-carboxylate;Z1200240828;7-Oxabicyclo[2.2.1]heptane-2-carboxylic acid methyl ester

Suppliers and Price of Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate

Chemical Property:

XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:156.078644241
Heavy Atom Count:11
Complexity:178

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1CC2CCC1O2

Technology Process of Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate

There total 3 articles about Methyl 7-oxabicyclo[2.2.1]heptane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 19800-01-2,38263-55-7,38263-56-8,64589-27-1
endo-2-Carboxy-7-oxabicyclo<2.2.1>heptan

: 17791-34-3,17791-35-4,21987-32-6,95931-58-1,95931-59-2,132747-22-9,132747-24-1
endo-2-Carbomethoxy-7-oxabicyclo<2.2.1>heptan

Guidance literature:: In diethyl ether;
DOI:10.1039/c39860000771

Reference yield:

: 90760-56-8
(-)-7-endo-oxabicyclo<2.2.1>hept-5-ene-2-carboxylic acid

: 17791-34-3,17791-35-4,21987-32-6,95931-58-1,95931-59-2,132747-22-9,132747-24-1
endo-2-Carbomethoxy-7-oxabicyclo<2.2.1>heptan

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / H₂ / Pd-C

2: 92 percent / diethyl ether

With hydrogen; palladium on activated charcoal; In diethyl ether;
DOI:10.1039/c39860000771

Reference yield:

: 17791-34-3,17791-35-4,21987-32-6,95931-58-1,95931-59-2,132747-22-9,132747-24-1
endo-2-Carbomethoxy-7-oxabicyclo<2.2.1>heptan

Guidance literature:: Mischg. endo- u. exo-2-Carbomethoxy-7-oxabicyclo<2.2.1>hept-5-en (9 u. 10), kat. Hydrierg. (neben d. exo-Isomeren);
DOI:10.1021/jm00290a007